High‐Performance Strain Sensors Based on Organohydrogel Microsphere Film for Wearable Human–Computer Interfacing

Stretchable hydrogel‐based strain sensors suffer from limited sensitivity, which urgently requires further breakthroughs for precise and stable human‐computer interaction. Here, an efficient microstructural engineering strategy is proposed to significantly enhance the sensitivity of hydrogel‐based strain sensors by sandwiching an emulsion‐polymerized polyacrylamide organohydrogel microsphere membrane between two Ecoflex films, which are accompanied by crack generation and propagation effects upon stretching. Consequently, the as‐developed strain sensor exhibits ultrahigh sensitivity (gauge factor (GF) of 1275), wide detection range (100% strain), low hysteresis, ultralow detection limit (0.05% strain), good fatigue resistance, and low fabrication cost. In addition, the sensor features good water, dehydration, and frost resistance, enabling real‐time strain monitoring in various complex conditions due to the encapsulation of Ecoflex film and the addition of glycerol and KCl. Through further structural manipulation, the device achieves superior response to tiny strains, with a GF value of 98.3 in the strain range of less than 1.5%. Owing to the high strain sensing performance, the sensor is able to detect various human activities from swallowing to finger bending even under water. On this basis, a wireless sensing system with apnea warning and single‐channel gesture recognition capabilities is successfully demonstrated, demonstrating its great promise as wearable electronics.