Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations

[Image: see text] Aryl trifluoromethyl diazoalkanes and diazirines have become unique as reactants in synthetic methodology. As privileged compounds containing CF(3) groups and ease of synthetic access, aryl trifluoromethyl diazoalkanes and diazirines have been highlighted for their versatility in a...

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Autores principales: Ollevier, Thierry, Carreras, Virginie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954246/
https://www.ncbi.nlm.nih.gov/pubmed/36855460
http://dx.doi.org/10.1021/acsorginorgau.1c00027
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author Ollevier, Thierry
Carreras, Virginie
author_facet Ollevier, Thierry
Carreras, Virginie
author_sort Ollevier, Thierry
collection PubMed
description [Image: see text] Aryl trifluoromethyl diazoalkanes and diazirines have become unique as reactants in synthetic methodology. As privileged compounds containing CF(3) groups and ease of synthetic access, aryl trifluoromethyl diazoalkanes and diazirines have been highlighted for their versatility in applications toward a wide range of synthetic transformations. This Perspective highlights the synthetic applications of these reactants as precursors of stabilized metal carbenes, i.e., donor–acceptor-substituted ones.
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spelling pubmed-99542462023-02-27 Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations Ollevier, Thierry Carreras, Virginie ACS Org Inorg Au [Image: see text] Aryl trifluoromethyl diazoalkanes and diazirines have become unique as reactants in synthetic methodology. As privileged compounds containing CF(3) groups and ease of synthetic access, aryl trifluoromethyl diazoalkanes and diazirines have been highlighted for their versatility in applications toward a wide range of synthetic transformations. This Perspective highlights the synthetic applications of these reactants as precursors of stabilized metal carbenes, i.e., donor–acceptor-substituted ones. American Chemical Society 2022-01-08 /pmc/articles/PMC9954246/ /pubmed/36855460 http://dx.doi.org/10.1021/acsorginorgau.1c00027 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Ollevier, Thierry
Carreras, Virginie
Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title_full Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title_fullStr Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title_full_unstemmed Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title_short Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
title_sort emerging applications of aryl trifluoromethyl diazoalkanes and diazirines in synthetic transformations
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954246/
https://www.ncbi.nlm.nih.gov/pubmed/36855460
http://dx.doi.org/10.1021/acsorginorgau.1c00027
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