Electrochemical Hydrosilylation of Alkynes

[Image: see text] Herein, the electrochemical hydrosilylation of alkynes is reported. In the presence of the Suginome reagent (PhMe(2)Si–Bpin), a large panel of terminal alkynes and internal alkynes was successfully converted into the hydrosilylated product in good to excellent yields and good selec...

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Detalles Bibliográficos
Autores principales: Biremond, Tony, Jubault, Philippe, Poisson, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954247/
https://www.ncbi.nlm.nih.gov/pubmed/36855456
http://dx.doi.org/10.1021/acsorginorgau.1c00035
Descripción
Sumario:[Image: see text] Herein, the electrochemical hydrosilylation of alkynes is reported. In the presence of the Suginome reagent (PhMe(2)Si–Bpin), a large panel of terminal alkynes and internal alkynes was successfully converted into the hydrosilylated product in good to excellent yields and good selectivity in favor of the linear product. Preliminary mechanistic study supported the involvement of a silyl radical, which reacted on the alkyne.

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