Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds

[Image: see text] Inspired by the strategy of fluorine introduction in borates and phosphates, the inorganic oxyfluoride (NH(4))(3)[PO(3)F][BF(4)] with B–F and P–F bonds has been characterized as the first fluoroborate-fluorophosphate. The International Union of Pure and Applied Chemistry (IUPAC) na...

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Autores principales: Qiu, Haotian, Cai, Wenbing, Yang, Zhihua, Liu, Yanli, Mutailipu, Miriding, Pan, Shilie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954260/
https://www.ncbi.nlm.nih.gov/pubmed/36855636
http://dx.doi.org/10.1021/acsorginorgau.1c00018
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author Qiu, Haotian
Cai, Wenbing
Yang, Zhihua
Liu, Yanli
Mutailipu, Miriding
Pan, Shilie
author_facet Qiu, Haotian
Cai, Wenbing
Yang, Zhihua
Liu, Yanli
Mutailipu, Miriding
Pan, Shilie
author_sort Qiu, Haotian
collection PubMed
description [Image: see text] Inspired by the strategy of fluorine introduction in borates and phosphates, the inorganic oxyfluoride (NH(4))(3)[PO(3)F][BF(4)] with B–F and P–F bonds has been characterized as the first fluoroborate-fluorophosphate. The International Union of Pure and Applied Chemistry (IUPAC) name for (NH(4))(3)[PO(3)F][BF(4)] should be ammonium tetrafluoroborate-monofluorophosphate according to the structure characteristics. The existence and coordination of fluorine in (NH(4))(3)[PO(3)F][BF(4)] were confirmed by several approaches, including single-crystal structure analysis; bond valence analysis; and X-ray energy dispersive, infrared spectrum, and also nuclear magnetic resonance spectroscopy. This work is of great significance to enrich the solid-state chemistry of borates and phosphates and also open a new branch of mixed anion compound with fluoroborate-fluorophosphates.
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spelling pubmed-99542602023-02-27 Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds Qiu, Haotian Cai, Wenbing Yang, Zhihua Liu, Yanli Mutailipu, Miriding Pan, Shilie ACS Org Inorg Au [Image: see text] Inspired by the strategy of fluorine introduction in borates and phosphates, the inorganic oxyfluoride (NH(4))(3)[PO(3)F][BF(4)] with B–F and P–F bonds has been characterized as the first fluoroborate-fluorophosphate. The International Union of Pure and Applied Chemistry (IUPAC) name for (NH(4))(3)[PO(3)F][BF(4)] should be ammonium tetrafluoroborate-monofluorophosphate according to the structure characteristics. The existence and coordination of fluorine in (NH(4))(3)[PO(3)F][BF(4)] were confirmed by several approaches, including single-crystal structure analysis; bond valence analysis; and X-ray energy dispersive, infrared spectrum, and also nuclear magnetic resonance spectroscopy. This work is of great significance to enrich the solid-state chemistry of borates and phosphates and also open a new branch of mixed anion compound with fluoroborate-fluorophosphates. American Chemical Society 2021-08-04 /pmc/articles/PMC9954260/ /pubmed/36855636 http://dx.doi.org/10.1021/acsorginorgau.1c00018 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Qiu, Haotian
Cai, Wenbing
Yang, Zhihua
Liu, Yanli
Mutailipu, Miriding
Pan, Shilie
Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title_full Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title_fullStr Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title_full_unstemmed Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title_short Tetrafluoroborate-Monofluorophosphate (NH(4))(3)[PO(3)F][BF(4)]: First Member of Oxyfluoride with B–F and P–F Bonds
title_sort tetrafluoroborate-monofluorophosphate (nh(4))(3)[po(3)f][bf(4)]: first member of oxyfluoride with b–f and p–f bonds
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954260/
https://www.ncbi.nlm.nih.gov/pubmed/36855636
http://dx.doi.org/10.1021/acsorginorgau.1c00018
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