Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses

[Image: see text] The formation of C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) bonds is one of the major research goals of synthetic chemists. Electrochemistry is commonly considered to be an appealing means to drive redox reactions in a safe and sustainable fashion and has been utilized for C–C bond-fo...

Descripción completa

Detalles Bibliográficos
Autores principales: Claraz, Aurélie, Masson, Géraldine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954344/
https://www.ncbi.nlm.nih.gov/pubmed/36855458
http://dx.doi.org/10.1021/acsorginorgau.1c00037
_version_ 1784894097250582528
author Claraz, Aurélie
Masson, Géraldine
author_facet Claraz, Aurélie
Masson, Géraldine
author_sort Claraz, Aurélie
collection PubMed
description [Image: see text] The formation of C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) bonds is one of the major research goals of synthetic chemists. Electrochemistry is commonly considered to be an appealing means to drive redox reactions in a safe and sustainable fashion and has been utilized for C–C bond-forming reactions. Compared to anodic oxidative methods, which have been extensively explored, cathodic processes are much less investigated, whereas it can pave the way to alternative retrosynthetic disconnections of target molecules and to the discovery of new transformations. This review provides an overview on the recent achievements in the construction of C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) bonds via cathodic reactions since 2017. It includes electrochemical reductions and convergent paired electrolyses.
format Online
Article
Text
id pubmed-9954344
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-99543442023-02-27 Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses Claraz, Aurélie Masson, Géraldine ACS Org Inorg Au [Image: see text] The formation of C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) bonds is one of the major research goals of synthetic chemists. Electrochemistry is commonly considered to be an appealing means to drive redox reactions in a safe and sustainable fashion and has been utilized for C–C bond-forming reactions. Compared to anodic oxidative methods, which have been extensively explored, cathodic processes are much less investigated, whereas it can pave the way to alternative retrosynthetic disconnections of target molecules and to the discovery of new transformations. This review provides an overview on the recent achievements in the construction of C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) bonds via cathodic reactions since 2017. It includes electrochemical reductions and convergent paired electrolyses. American Chemical Society 2021-12-22 /pmc/articles/PMC9954344/ /pubmed/36855458 http://dx.doi.org/10.1021/acsorginorgau.1c00037 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Claraz, Aurélie
Masson, Géraldine
Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title_full Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title_fullStr Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title_full_unstemmed Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title_short Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
title_sort recent advances in c(sp(3))–c(sp(3)) and c(sp(3))–c(sp(2)) bond formation through cathodic reactions: reductive and convergent paired electrolyses
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954344/
https://www.ncbi.nlm.nih.gov/pubmed/36855458
http://dx.doi.org/10.1021/acsorginorgau.1c00037
work_keys_str_mv AT clarazaurelie recentadvancesincsp3csp3andcsp3csp2bondformationthroughcathodicreactionsreductiveandconvergentpairedelectrolyses
AT massongeraldine recentadvancesincsp3csp3andcsp3csp2bondformationthroughcathodicreactionsreductiveandconvergentpairedelectrolyses

Ejemplares similares