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Organic Host Encapsulation Effects on Nitrosobenzene Monomer–Dimer Distribution and C–NO Bond Rotation in an Aqueous Solution

[Image: see text] The intermolecular (monomer–dimer equilibrium) and intramolecular (C–NO and C–NMe(2) rotations) dynamics of 4-nitrosocumene (1a) and 4-(N,N-dimethylamino)nitrosobenzene (1b), respectively, were found to be controlled by the medium (water) and the host environment (organic capsules...

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Detalles Bibliográficos
Autores principales: Varadharajan, Ramkumar, Kelley, Sarah Ariel, Jayasinghe-Arachchige, Vindi M., Prabhakar, Rajeev, Ramamurthy, Vaidhyanathan, Blackstock, Silas C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954408/
https://www.ncbi.nlm.nih.gov/pubmed/36855459
http://dx.doi.org/10.1021/acsorginorgau.1c00043