Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System

[Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–accep...

Descripción completa

Detalles Bibliográficos
Autores principales: Uchikura, Tatsuhiro, Hara, Yurina, Tsubono, Kazushi, Akiyama, Takahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954416/
https://www.ncbi.nlm.nih.gov/pubmed/36855634
http://dx.doi.org/10.1021/acsorginorgau.1c00007
Descripción
Sumario:[Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical.

Ejemplares similares