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Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System

[Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–accep...

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Autores principales: Uchikura, Tatsuhiro, Hara, Yurina, Tsubono, Kazushi, Akiyama, Takahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954416/
https://www.ncbi.nlm.nih.gov/pubmed/36855634
http://dx.doi.org/10.1021/acsorginorgau.1c00007
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author Uchikura, Tatsuhiro
Hara, Yurina
Tsubono, Kazushi
Akiyama, Takahiko
author_facet Uchikura, Tatsuhiro
Hara, Yurina
Tsubono, Kazushi
Akiyama, Takahiko
author_sort Uchikura, Tatsuhiro
collection PubMed
description [Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical.
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spelling pubmed-99544162023-02-27 Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System Uchikura, Tatsuhiro Hara, Yurina Tsubono, Kazushi Akiyama, Takahiko ACS Org Inorg Au [Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical. American Chemical Society 2021-06-22 /pmc/articles/PMC9954416/ /pubmed/36855634 http://dx.doi.org/10.1021/acsorginorgau.1c00007 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Uchikura, Tatsuhiro
Hara, Yurina
Tsubono, Kazushi
Akiyama, Takahiko
Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title_full Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title_fullStr Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title_full_unstemmed Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title_short Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
title_sort visible-light-driven c–s bond formation based on electron donor–acceptor excitation and hydrogen atom transfer combined system
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954416/
https://www.ncbi.nlm.nih.gov/pubmed/36855634
http://dx.doi.org/10.1021/acsorginorgau.1c00007
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