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Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System
[Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–accep...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954416/ https://www.ncbi.nlm.nih.gov/pubmed/36855634 http://dx.doi.org/10.1021/acsorginorgau.1c00007 |
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author | Uchikura, Tatsuhiro Hara, Yurina Tsubono, Kazushi Akiyama, Takahiko |
author_facet | Uchikura, Tatsuhiro Hara, Yurina Tsubono, Kazushi Akiyama, Takahiko |
author_sort | Uchikura, Tatsuhiro |
collection | PubMed |
description | [Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical. |
format | Online Article Text |
id | pubmed-9954416 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical
Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-99544162023-02-27 Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System Uchikura, Tatsuhiro Hara, Yurina Tsubono, Kazushi Akiyama, Takahiko ACS Org Inorg Au [Image: see text] Developed herein is a visible-light-driven synthesis of sulfides by an electron donor–acceptor/single electron transfer and hydrogen atom transfer combined system without transition metals and strong oxidants. This reaction proceeds through the excitation of an electron donor–acceptor complex between a thiolate and an aryl halide, followed by the hydrogen atom transfer from an alkane to the generated aryl radical. American Chemical Society 2021-06-22 /pmc/articles/PMC9954416/ /pubmed/36855634 http://dx.doi.org/10.1021/acsorginorgau.1c00007 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Uchikura, Tatsuhiro Hara, Yurina Tsubono, Kazushi Akiyama, Takahiko Visible-Light-Driven C–S Bond Formation Based on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer Combined System |
title | Visible-Light-Driven C–S Bond Formation Based
on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer
Combined System |
title_full | Visible-Light-Driven C–S Bond Formation Based
on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer
Combined System |
title_fullStr | Visible-Light-Driven C–S Bond Formation Based
on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer
Combined System |
title_full_unstemmed | Visible-Light-Driven C–S Bond Formation Based
on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer
Combined System |
title_short | Visible-Light-Driven C–S Bond Formation Based
on Electron Donor–Acceptor Excitation and Hydrogen Atom Transfer
Combined System |
title_sort | visible-light-driven c–s bond formation based
on electron donor–acceptor excitation and hydrogen atom transfer
combined system |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9954416/ https://www.ncbi.nlm.nih.gov/pubmed/36855634 http://dx.doi.org/10.1021/acsorginorgau.1c00007 |
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