Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex

[Image: see text] A synthetically beneficial visible-light-mediated protocol has been disclosed to achieve C–H amination of readily available feedstocks cyclic and acyclic ethers. A rarely identified N-bromosuccinamide–tetrahydrofuran electron donor–acceptor complex served as an initiator to functio...

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Autores principales: Roy, Sourav, Chatterjee, Indranil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955270/
https://www.ncbi.nlm.nih.gov/pubmed/36855592
http://dx.doi.org/10.1021/acsorginorgau.2c00008
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author Roy, Sourav
Chatterjee, Indranil
author_facet Roy, Sourav
Chatterjee, Indranil
author_sort Roy, Sourav
collection PubMed
description [Image: see text] A synthetically beneficial visible-light-mediated protocol has been disclosed to achieve C–H amination of readily available feedstocks cyclic and acyclic ethers. A rarely identified N-bromosuccinamide–tetrahydrofuran electron donor–acceptor complex served as an initiator to functionalize both α-diazoketones and dialkyl azodicarboxylates. This developed methodology gives an alternative and milder way to construct the C–N bond and can be explored for the formation of C–C bond to perform arylation and allylation reactions.
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spelling pubmed-99552702023-02-27 Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex Roy, Sourav Chatterjee, Indranil ACS Org Inorg Au [Image: see text] A synthetically beneficial visible-light-mediated protocol has been disclosed to achieve C–H amination of readily available feedstocks cyclic and acyclic ethers. A rarely identified N-bromosuccinamide–tetrahydrofuran electron donor–acceptor complex served as an initiator to functionalize both α-diazoketones and dialkyl azodicarboxylates. This developed methodology gives an alternative and milder way to construct the C–N bond and can be explored for the formation of C–C bond to perform arylation and allylation reactions. American Chemical Society 2022-03-29 /pmc/articles/PMC9955270/ /pubmed/36855592 http://dx.doi.org/10.1021/acsorginorgau.2c00008 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Roy, Sourav
Chatterjee, Indranil
Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title_full Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title_fullStr Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title_full_unstemmed Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title_short Visible-Light-Mediated (sp(3))Cα–H Functionalization of Ethers Enabled by Electron Donor–Acceptor Complex
title_sort visible-light-mediated (sp(3))cα–h functionalization of ethers enabled by electron donor–acceptor complex
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955270/
https://www.ncbi.nlm.nih.gov/pubmed/36855592
http://dx.doi.org/10.1021/acsorginorgau.2c00008
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