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Single-Ion Behavior in New 2-D and 3-D Gadolinium 4f(7) Materials: CsGd(SO(4))(2) and Cs[Gd(H(2)O)(3)(SO(4))(2)]·H(2)O
[Image: see text] The recent creation of 4f(7) gadolinium materials has enabled vital studies of the free-ion properties of the Gd(III) cations. While the (8)S ground state in a trivalent Gd compound is, in principle, isotropic, it has been demonstrated that there is a residual orbital angular momen...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9955392/ https://www.ncbi.nlm.nih.gov/pubmed/36855531 http://dx.doi.org/10.1021/acsorginorgau.2c00031 |