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Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic technique...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9957867/ https://www.ncbi.nlm.nih.gov/pubmed/36435905 http://dx.doi.org/10.1007/s10895-022-03085-z |
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author | Tohamy, Hebat‑Allah S. El‑Sakhawy, Mohamed Kamel, Samir |
author_facet | Tohamy, Hebat‑Allah S. El‑Sakhawy, Mohamed Kamel, Samir |
author_sort | Tohamy, Hebat‑Allah S. |
collection | PubMed |
description | Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R(2), the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB. |
format | Online Article Text |
id | pubmed-9957867 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Springer US |
record_format | MEDLINE/PubMed |
spelling | pubmed-99578672023-02-26 Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent Tohamy, Hebat‑Allah S. El‑Sakhawy, Mohamed Kamel, Samir J Fluoresc Research Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R(2), the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB. Springer US 2022-11-26 2023 /pmc/articles/PMC9957867/ /pubmed/36435905 http://dx.doi.org/10.1007/s10895-022-03085-z Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Research Tohamy, Hebat‑Allah S. El‑Sakhawy, Mohamed Kamel, Samir Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title | Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title_full | Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title_fullStr | Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title_full_unstemmed | Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title_short | Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent |
title_sort | eco-friendly synthesis of carbon quantum dots as an effective adsorbent |
topic | Research |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9957867/ https://www.ncbi.nlm.nih.gov/pubmed/36435905 http://dx.doi.org/10.1007/s10895-022-03085-z |
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