Cargando…

Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent

Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic technique...

Descripción completa

Detalles Bibliográficos
Autores principales: Tohamy, Hebat‑Allah S., El‑Sakhawy, Mohamed, Kamel, Samir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9957867/
https://www.ncbi.nlm.nih.gov/pubmed/36435905
http://dx.doi.org/10.1007/s10895-022-03085-z
_version_ 1784894915371597824
author Tohamy, Hebat‑Allah S.
El‑Sakhawy, Mohamed
Kamel, Samir
author_facet Tohamy, Hebat‑Allah S.
El‑Sakhawy, Mohamed
Kamel, Samir
author_sort Tohamy, Hebat‑Allah S.
collection PubMed
description Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R(2), the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB.
format Online
Article
Text
id pubmed-9957867
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-99578672023-02-26 Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent Tohamy, Hebat‑Allah S. El‑Sakhawy, Mohamed Kamel, Samir J Fluoresc Research Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R(2), the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB. Springer US 2022-11-26 2023 /pmc/articles/PMC9957867/ /pubmed/36435905 http://dx.doi.org/10.1007/s10895-022-03085-z Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Research
Tohamy, Hebat‑Allah S.
El‑Sakhawy, Mohamed
Kamel, Samir
Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title_full Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title_fullStr Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title_full_unstemmed Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title_short Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent
title_sort eco-friendly synthesis of carbon quantum dots as an effective adsorbent
topic Research
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9957867/
https://www.ncbi.nlm.nih.gov/pubmed/36435905
http://dx.doi.org/10.1007/s10895-022-03085-z
work_keys_str_mv AT tohamyhebatallahs ecofriendlysynthesisofcarbonquantumdotsasaneffectiveadsorbent
AT elsakhawymohamed ecofriendlysynthesisofcarbonquantumdotsasaneffectiveadsorbent
AT kamelsamir ecofriendlysynthesisofcarbonquantumdotsasaneffectiveadsorbent