Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles

In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe(3)O(4)] has been successfully developed. The synthesized complex was analyzed usin...

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Autores principales: Nasrollahzadeh, Mahmoud, Motahharifar, Narjes, Pakzad, Khatereh, Khorsandi, Zahra, Baran, Talat, Wang, Jinghan, Kruppke, Benjamin, Khonakdar, Hossein Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9958043/
https://www.ncbi.nlm.nih.gov/pubmed/36828906
http://dx.doi.org/10.1038/s41598-023-30198-7
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author Nasrollahzadeh, Mahmoud
Motahharifar, Narjes
Pakzad, Khatereh
Khorsandi, Zahra
Baran, Talat
Wang, Jinghan
Kruppke, Benjamin
Khonakdar, Hossein Ali
author_facet Nasrollahzadeh, Mahmoud
Motahharifar, Narjes
Pakzad, Khatereh
Khorsandi, Zahra
Baran, Talat
Wang, Jinghan
Kruppke, Benjamin
Khonakdar, Hossein Ali
author_sort Nasrollahzadeh, Mahmoud
collection PubMed
description In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe(3)O(4)] has been successfully developed. The synthesized complex was analyzed using TEM (transmission electron microscopy), HRTEM (high resolution-transmission electron microscopy), STEM (scanning transmission electron microscopy), FFT (Fast Fourier transform), XRD (X-ray diffraction), FT-IR (Fourier transform-infrared spectroscopy), TG/DTG (Thermogravimetry and differential thermogravimetry), ICP-OES (Inductively coupled plasma-optical emission spectrometry), Vibrating sample magnetometer (VSM), EDS (energy dispersive X-ray spectroscopy), and elemental mapping. N-Sulfonyl-N-aryl tetrazoles were synthesized in high yields from N-sulfonyl-N-aryl cyanamides and sodium azide using Ps@Tet-Cu(II)@Fe(3)O(4) nanocatalyst. The Ps@Tet-Cu(II)@Fe(3)O(4) complex can be recycled and reused easily multiple times using an external magnet without significant loss of catalytic activity.
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spelling pubmed-99580432023-02-26 Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles Nasrollahzadeh, Mahmoud Motahharifar, Narjes Pakzad, Khatereh Khorsandi, Zahra Baran, Talat Wang, Jinghan Kruppke, Benjamin Khonakdar, Hossein Ali Sci Rep Article In this work, a cost-effective, environmentally friendly, and convenient method for synthesizing a novel heterogeneous catalyst via modification of polystyrene using tetrazole-copper magnetic complex [Ps@Tet-Cu(II)@Fe(3)O(4)] has been successfully developed. The synthesized complex was analyzed using TEM (transmission electron microscopy), HRTEM (high resolution-transmission electron microscopy), STEM (scanning transmission electron microscopy), FFT (Fast Fourier transform), XRD (X-ray diffraction), FT-IR (Fourier transform-infrared spectroscopy), TG/DTG (Thermogravimetry and differential thermogravimetry), ICP-OES (Inductively coupled plasma-optical emission spectrometry), Vibrating sample magnetometer (VSM), EDS (energy dispersive X-ray spectroscopy), and elemental mapping. N-Sulfonyl-N-aryl tetrazoles were synthesized in high yields from N-sulfonyl-N-aryl cyanamides and sodium azide using Ps@Tet-Cu(II)@Fe(3)O(4) nanocatalyst. The Ps@Tet-Cu(II)@Fe(3)O(4) complex can be recycled and reused easily multiple times using an external magnet without significant loss of catalytic activity. Nature Publishing Group UK 2023-02-24 /pmc/articles/PMC9958043/ /pubmed/36828906 http://dx.doi.org/10.1038/s41598-023-30198-7 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Nasrollahzadeh, Mahmoud
Motahharifar, Narjes
Pakzad, Khatereh
Khorsandi, Zahra
Baran, Talat
Wang, Jinghan
Kruppke, Benjamin
Khonakdar, Hossein Ali
Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title_full Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title_fullStr Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title_full_unstemmed Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title_short Synthesis of a magnetic polystyrene-supported Cu(II)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of N-sulfonyl-N-aryl tetrazoles
title_sort synthesis of a magnetic polystyrene-supported cu(ii)-containing heterocyclic complex as a magnetically separable and reusable catalyst for the preparation of n-sulfonyl-n-aryl tetrazoles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9958043/
https://www.ncbi.nlm.nih.gov/pubmed/36828906
http://dx.doi.org/10.1038/s41598-023-30198-7
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