Electrospun Membranes Anchored with g-C(3)N(4)/MoS(2) for Highly Efficient Photocatalytic Degradation of Aflatoxin B(1) under Visible Light

The degradation of aflatoxin (AF) is a topic that always exists along with the food and feed industry. Photocatalytic degradation as an advanced oxidation technology has many benefits, including complete inorganic degradation, no secondary contamination, ease of activity under moderate conditions, and low cost compared with traditional physical, chemical, and biological strategies. However, photocatalysts are usually dispersed during photocatalytic reactions, resulting in energy and time consumption in the separation process. There is even a potential secondary pollution problem from the perspective of food safety. In this regard, three electrospun membranes anchored with g-C(3)N(4)/MoS(2) composites were prepared for highly efficient photocatalytic degradation of aflatoxin B(1) (AFB(1)) under visible light. These photocatalytic membranes were characterized by XRD, SEM, TEM, FTIR, and XPS. The factors influencing the degradation efficiency of AFB(1), including pH values and initial concentrations, were also probed. The three kinds of photocatalytic membranes all exhibited excellent ability to degrade AFB(1). Among them, the photocatalytic degradation efficiency of the photocatalytic membranes prepared by the coaxial methods reached 96.8%. The experiment is with an initial concentration of 0.5 μg/mL (500 PPb) after 60 min under visible light irradiation. The mechanism of degradation of AFB(1) was also proposed based on active species trapping experiments. Moreover, the prepared photocatalytic membranes exhibited excellent photocatalytic activity even after five-fold use in the degradation of AFB(1). These studies showed that electrospun membranes anchored with g-C(3)N(4)/MoS(2) composites have a high photocatalytic ability which is easily removed from the reacted medium for reuse. Thereby, our study offers a highly effective, economical, and green solution for AFB(1) degradation in the foodstuff for practical application.