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Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes

High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal stru...

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Autores principales: Chiu, Sheng-Kuei, Chen, Po-Yan, Louh, Rong-Fuh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9961811/
https://www.ncbi.nlm.nih.gov/pubmed/36838061
http://dx.doi.org/10.3390/mi14020361
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author Chiu, Sheng-Kuei
Chen, Po-Yan
Louh, Rong-Fuh
author_facet Chiu, Sheng-Kuei
Chen, Po-Yan
Louh, Rong-Fuh
author_sort Chiu, Sheng-Kuei
collection PubMed
description High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal structure (IOS) photonic crystal, of which the structural thickness can be freely adjusted via electrochemical deposition (ECD), and subsequently, MnS/MoS(2)/Ni-IOS specimens were also prepared by ECD. Excellent specific capacitance values (1880 F/g) were obtained at a charge current density of 5 A/g. The samples in this experiment were tested for 2000 cycles of cycle life and still retained a reasonably good level of 76.6% of their initial capacitance value. In this study, the inverse opal structure photonic crystal substrate was used as the starting point, and then the microelectrode material for the MnS/MoS(2)/Ni-IOS supercapacitor was synthesized. Our findings show that the MnS/MoS(2)/Ni-IOS microelectrode makes a viable technical contribution to the design and fabrication of high-performance supercapacitors.
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spelling pubmed-99618112023-02-26 Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes Chiu, Sheng-Kuei Chen, Po-Yan Louh, Rong-Fuh Micromachines (Basel) Article High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal structure (IOS) photonic crystal, of which the structural thickness can be freely adjusted via electrochemical deposition (ECD), and subsequently, MnS/MoS(2)/Ni-IOS specimens were also prepared by ECD. Excellent specific capacitance values (1880 F/g) were obtained at a charge current density of 5 A/g. The samples in this experiment were tested for 2000 cycles of cycle life and still retained a reasonably good level of 76.6% of their initial capacitance value. In this study, the inverse opal structure photonic crystal substrate was used as the starting point, and then the microelectrode material for the MnS/MoS(2)/Ni-IOS supercapacitor was synthesized. Our findings show that the MnS/MoS(2)/Ni-IOS microelectrode makes a viable technical contribution to the design and fabrication of high-performance supercapacitors. MDPI 2023-01-31 /pmc/articles/PMC9961811/ /pubmed/36838061 http://dx.doi.org/10.3390/mi14020361 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chiu, Sheng-Kuei
Chen, Po-Yan
Louh, Rong-Fuh
Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title_full Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title_fullStr Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title_full_unstemmed Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title_short Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
title_sort electrochemically deposited mos(2) and mns multilayers on nickel substrates in inverse opal structure as supercapacitor microelectrodes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9961811/
https://www.ncbi.nlm.nih.gov/pubmed/36838061
http://dx.doi.org/10.3390/mi14020361
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AT chenpoyan electrochemicallydepositedmos2andmnsmultilayersonnickelsubstratesininverseopalstructureassupercapacitormicroelectrodes
AT louhrongfuh electrochemicallydepositedmos2andmnsmultilayersonnickelsubstratesininverseopalstructureassupercapacitormicroelectrodes