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Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes
High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal stru...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9961811/ https://www.ncbi.nlm.nih.gov/pubmed/36838061 http://dx.doi.org/10.3390/mi14020361 |
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author | Chiu, Sheng-Kuei Chen, Po-Yan Louh, Rong-Fuh |
author_facet | Chiu, Sheng-Kuei Chen, Po-Yan Louh, Rong-Fuh |
author_sort | Chiu, Sheng-Kuei |
collection | PubMed |
description | High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal structure (IOS) photonic crystal, of which the structural thickness can be freely adjusted via electrochemical deposition (ECD), and subsequently, MnS/MoS(2)/Ni-IOS specimens were also prepared by ECD. Excellent specific capacitance values (1880 F/g) were obtained at a charge current density of 5 A/g. The samples in this experiment were tested for 2000 cycles of cycle life and still retained a reasonably good level of 76.6% of their initial capacitance value. In this study, the inverse opal structure photonic crystal substrate was used as the starting point, and then the microelectrode material for the MnS/MoS(2)/Ni-IOS supercapacitor was synthesized. Our findings show that the MnS/MoS(2)/Ni-IOS microelectrode makes a viable technical contribution to the design and fabrication of high-performance supercapacitors. |
format | Online Article Text |
id | pubmed-9961811 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-99618112023-02-26 Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes Chiu, Sheng-Kuei Chen, Po-Yan Louh, Rong-Fuh Micromachines (Basel) Article High-dispersion polystyrene (PS) microspheres with monodispersity were successfully synthesized by the non-emulsification polymerization method, and three-dimensional (3D) photonic crystals of PS microspheres were fabricated by electrophoretic self-assembly (EPSA). The metal nickel inverse opal structure (IOS) photonic crystal, of which the structural thickness can be freely adjusted via electrochemical deposition (ECD), and subsequently, MnS/MoS(2)/Ni-IOS specimens were also prepared by ECD. Excellent specific capacitance values (1880 F/g) were obtained at a charge current density of 5 A/g. The samples in this experiment were tested for 2000 cycles of cycle life and still retained a reasonably good level of 76.6% of their initial capacitance value. In this study, the inverse opal structure photonic crystal substrate was used as the starting point, and then the microelectrode material for the MnS/MoS(2)/Ni-IOS supercapacitor was synthesized. Our findings show that the MnS/MoS(2)/Ni-IOS microelectrode makes a viable technical contribution to the design and fabrication of high-performance supercapacitors. MDPI 2023-01-31 /pmc/articles/PMC9961811/ /pubmed/36838061 http://dx.doi.org/10.3390/mi14020361 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Chiu, Sheng-Kuei Chen, Po-Yan Louh, Rong-Fuh Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title | Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title_full | Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title_fullStr | Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title_full_unstemmed | Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title_short | Electrochemically Deposited MoS(2) and MnS Multilayers on Nickel Substrates in Inverse Opal Structure as Supercapacitor Microelectrodes |
title_sort | electrochemically deposited mos(2) and mns multilayers on nickel substrates in inverse opal structure as supercapacitor microelectrodes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9961811/ https://www.ncbi.nlm.nih.gov/pubmed/36838061 http://dx.doi.org/10.3390/mi14020361 |
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