Cargando…

On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study

The performance of an anion exchange membrane water electrolyzer under various operational conditions (including voltage, KOH-supporting electrolyte concentration, and flow rate) is studied using conventional time-domain technics and electrochemical impedance spectroscopy (EIS). The water electrolyz...

Descripción completa

Detalles Bibliográficos
Autores principales: Pushkareva, Irina V., Solovyev, Maksim A., Butrim, Sergey I., Kozlova, Margarita V., Simkin, Dmitri A., Pushkarev, Artem S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9966502/
https://www.ncbi.nlm.nih.gov/pubmed/36837694
http://dx.doi.org/10.3390/membranes13020192
_version_ 1784897033245556736
author Pushkareva, Irina V.
Solovyev, Maksim A.
Butrim, Sergey I.
Kozlova, Margarita V.
Simkin, Dmitri A.
Pushkarev, Artem S.
author_facet Pushkareva, Irina V.
Solovyev, Maksim A.
Butrim, Sergey I.
Kozlova, Margarita V.
Simkin, Dmitri A.
Pushkarev, Artem S.
author_sort Pushkareva, Irina V.
collection PubMed
description The performance of an anion exchange membrane water electrolyzer under various operational conditions (including voltage, KOH-supporting electrolyte concentration, and flow rate) is studied using conventional time-domain technics and electrochemical impedance spectroscopy (EIS). The water electrolyzer EIS footprint, depending on the variation in operational conditions, is studied and discussed, providing valuable data on the faradaic and non-faradaic processes in MEA, considering their contribution to the total polarization resistance. The distribution of the AEMWE cell voltage contributions is valuable to accessing the key directions in the system performance improvement.
format Online
Article
Text
id pubmed-9966502
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-99665022023-02-26 On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study Pushkareva, Irina V. Solovyev, Maksim A. Butrim, Sergey I. Kozlova, Margarita V. Simkin, Dmitri A. Pushkarev, Artem S. Membranes (Basel) Article The performance of an anion exchange membrane water electrolyzer under various operational conditions (including voltage, KOH-supporting electrolyte concentration, and flow rate) is studied using conventional time-domain technics and electrochemical impedance spectroscopy (EIS). The water electrolyzer EIS footprint, depending on the variation in operational conditions, is studied and discussed, providing valuable data on the faradaic and non-faradaic processes in MEA, considering their contribution to the total polarization resistance. The distribution of the AEMWE cell voltage contributions is valuable to accessing the key directions in the system performance improvement. MDPI 2023-02-03 /pmc/articles/PMC9966502/ /pubmed/36837694 http://dx.doi.org/10.3390/membranes13020192 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pushkareva, Irina V.
Solovyev, Maksim A.
Butrim, Sergey I.
Kozlova, Margarita V.
Simkin, Dmitri A.
Pushkarev, Artem S.
On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title_full On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title_fullStr On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title_full_unstemmed On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title_short On the Operational Conditions’ Effect on the Performance of an Anion Exchange Membrane Water Electrolyzer: Electrochemical Impedance Spectroscopy Study
title_sort on the operational conditions’ effect on the performance of an anion exchange membrane water electrolyzer: electrochemical impedance spectroscopy study
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9966502/
https://www.ncbi.nlm.nih.gov/pubmed/36837694
http://dx.doi.org/10.3390/membranes13020192
work_keys_str_mv AT pushkarevairinav ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy
AT solovyevmaksima ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy
AT butrimsergeyi ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy
AT kozlovamargaritav ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy
AT simkindmitria ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy
AT pushkarevartems ontheoperationalconditionseffectontheperformanceofananionexchangemembranewaterelectrolyzerelectrochemicalimpedancespectroscopystudy