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Direct Recycling of WC-Co Grinding Chip

Grinding is a finishing process for high precision, high surface quality parts, and hard materials, including tool fabrication and sharpening. The recycling of grinding scraps, which often contain rare and costly materials such as tungsten carbide (WC-Co), has been established for decades. However,...

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Autores principales: Pacini, Alessio, Lupi, Francesco, Rossi, Andrea, Seggiani, Maurizia, Lanzetta, Michele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967445/
https://www.ncbi.nlm.nih.gov/pubmed/36836977
http://dx.doi.org/10.3390/ma16041347
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author Pacini, Alessio
Lupi, Francesco
Rossi, Andrea
Seggiani, Maurizia
Lanzetta, Michele
author_facet Pacini, Alessio
Lupi, Francesco
Rossi, Andrea
Seggiani, Maurizia
Lanzetta, Michele
author_sort Pacini, Alessio
collection PubMed
description Grinding is a finishing process for high precision, high surface quality parts, and hard materials, including tool fabrication and sharpening. The recycling of grinding scraps, which often contain rare and costly materials such as tungsten carbide (WC-Co), has been established for decades. However, there is a growing need for more energy-efficient and environmentally friendly recycling processes. Currently, grinding sludges, which are a mixture of abrasives, lubricants, and hard metal chips, are only treated through chemical recycling. Direct recycling (“reuse” of chips as raw material) is the most effective but not yet viable process due to the presence of contaminants. This paper presents an oil-free dry grinding process that produces high-quality chips (i.e., oil-free and with few contaminants, smaller than 60 mesh particle size) that can be directly recycled, as opposed to the oil-based wet grinding that generates sludges, which require indirect recycling. The proposed alternative recycling method is validated experimentally using WC-Co chips from a leading hard metals’ processing specialized company. The contaminant level (oxygen 0.8 wt.%, others < 0.4 wt.%), granulometry (chip D50 = 10.4 µm with grain size < 3 µm) and morphology of the recycled chips’ powder is comparable to commercial powders proving the research and industrial potential of direct recycling. The comparison of sintered products using recycled and commercial powder provided equivalent characteristics for hardness (HRA of 90.7, HV30 of 1430), porosity grade (A02-04) and grain size (<3 µm).
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spelling pubmed-99674452023-02-27 Direct Recycling of WC-Co Grinding Chip Pacini, Alessio Lupi, Francesco Rossi, Andrea Seggiani, Maurizia Lanzetta, Michele Materials (Basel) Article Grinding is a finishing process for high precision, high surface quality parts, and hard materials, including tool fabrication and sharpening. The recycling of grinding scraps, which often contain rare and costly materials such as tungsten carbide (WC-Co), has been established for decades. However, there is a growing need for more energy-efficient and environmentally friendly recycling processes. Currently, grinding sludges, which are a mixture of abrasives, lubricants, and hard metal chips, are only treated through chemical recycling. Direct recycling (“reuse” of chips as raw material) is the most effective but not yet viable process due to the presence of contaminants. This paper presents an oil-free dry grinding process that produces high-quality chips (i.e., oil-free and with few contaminants, smaller than 60 mesh particle size) that can be directly recycled, as opposed to the oil-based wet grinding that generates sludges, which require indirect recycling. The proposed alternative recycling method is validated experimentally using WC-Co chips from a leading hard metals’ processing specialized company. The contaminant level (oxygen 0.8 wt.%, others < 0.4 wt.%), granulometry (chip D50 = 10.4 µm with grain size < 3 µm) and morphology of the recycled chips’ powder is comparable to commercial powders proving the research and industrial potential of direct recycling. The comparison of sintered products using recycled and commercial powder provided equivalent characteristics for hardness (HRA of 90.7, HV30 of 1430), porosity grade (A02-04) and grain size (<3 µm). MDPI 2023-02-05 /pmc/articles/PMC9967445/ /pubmed/36836977 http://dx.doi.org/10.3390/ma16041347 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Pacini, Alessio
Lupi, Francesco
Rossi, Andrea
Seggiani, Maurizia
Lanzetta, Michele
Direct Recycling of WC-Co Grinding Chip
title Direct Recycling of WC-Co Grinding Chip
title_full Direct Recycling of WC-Co Grinding Chip
title_fullStr Direct Recycling of WC-Co Grinding Chip
title_full_unstemmed Direct Recycling of WC-Co Grinding Chip
title_short Direct Recycling of WC-Co Grinding Chip
title_sort direct recycling of wc-co grinding chip
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967445/
https://www.ncbi.nlm.nih.gov/pubmed/36836977
http://dx.doi.org/10.3390/ma16041347
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