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Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroa...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967660/ https://www.ncbi.nlm.nih.gov/pubmed/36850282 http://dx.doi.org/10.3390/polym15041000 |
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author | Shan, Tilun Bian, Huiguang Zhu, Donglin Wang, Kongshuo Wang, Chuansheng Tian, Xiaolong |
author_facet | Shan, Tilun Bian, Huiguang Zhu, Donglin Wang, Kongshuo Wang, Chuansheng Tian, Xiaolong |
author_sort | Shan, Tilun |
collection | PubMed |
description | Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroad. To this end, this paper conducted a mechanistic and experimental study on the replacement of some carbon blacks by spent FCC catalysts for the preparation of rubber products and explored the synergistic reinforcing effect of spent catalysts and carbon blacks, in order to extend the reuse methods of spent catalysts and reduce the pollution caused by them to the environment. The experimental results demonstrated that the filler dispersion and distribution in the compound are more uniform after replacing the carbon black with modified spent FCC catalysts. The crosslinking density of rubber increases, the Payne effect is decreased, and the dynamic mechanical properties and aging resistance are improved. When the number of replacement parts reached 15, the comprehensive performance of the rubber composites remained the same as that of the control group. In this paper, the spent FCC catalysts modified by the physical method instead of the carbon-black-filled SBR can not only improve the performance of rubber products, but also can provide basic technical and theoretical support to realize the recycling of spent FCC catalysts and reduce the environmental pressure. The feasibility of preparing rubber composites by spent catalysts is also verified. |
format | Online Article Text |
id | pubmed-9967660 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-99676602023-02-27 Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst Shan, Tilun Bian, Huiguang Zhu, Donglin Wang, Kongshuo Wang, Chuansheng Tian, Xiaolong Polymers (Basel) Article Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroad. To this end, this paper conducted a mechanistic and experimental study on the replacement of some carbon blacks by spent FCC catalysts for the preparation of rubber products and explored the synergistic reinforcing effect of spent catalysts and carbon blacks, in order to extend the reuse methods of spent catalysts and reduce the pollution caused by them to the environment. The experimental results demonstrated that the filler dispersion and distribution in the compound are more uniform after replacing the carbon black with modified spent FCC catalysts. The crosslinking density of rubber increases, the Payne effect is decreased, and the dynamic mechanical properties and aging resistance are improved. When the number of replacement parts reached 15, the comprehensive performance of the rubber composites remained the same as that of the control group. In this paper, the spent FCC catalysts modified by the physical method instead of the carbon-black-filled SBR can not only improve the performance of rubber products, but also can provide basic technical and theoretical support to realize the recycling of spent FCC catalysts and reduce the environmental pressure. The feasibility of preparing rubber composites by spent catalysts is also verified. MDPI 2023-02-17 /pmc/articles/PMC9967660/ /pubmed/36850282 http://dx.doi.org/10.3390/polym15041000 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Shan, Tilun Bian, Huiguang Zhu, Donglin Wang, Kongshuo Wang, Chuansheng Tian, Xiaolong Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title | Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title_full | Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title_fullStr | Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title_full_unstemmed | Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title_short | Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst |
title_sort | study on the mechanism and experiment of styrene butadiene rubber reinforcement by spent fluid catalytic cracking catalyst |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967660/ https://www.ncbi.nlm.nih.gov/pubmed/36850282 http://dx.doi.org/10.3390/polym15041000 |
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