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Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst

Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroa...

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Autores principales: Shan, Tilun, Bian, Huiguang, Zhu, Donglin, Wang, Kongshuo, Wang, Chuansheng, Tian, Xiaolong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967660/
https://www.ncbi.nlm.nih.gov/pubmed/36850282
http://dx.doi.org/10.3390/polym15041000
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author Shan, Tilun
Bian, Huiguang
Zhu, Donglin
Wang, Kongshuo
Wang, Chuansheng
Tian, Xiaolong
author_facet Shan, Tilun
Bian, Huiguang
Zhu, Donglin
Wang, Kongshuo
Wang, Chuansheng
Tian, Xiaolong
author_sort Shan, Tilun
collection PubMed
description Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroad. To this end, this paper conducted a mechanistic and experimental study on the replacement of some carbon blacks by spent FCC catalysts for the preparation of rubber products and explored the synergistic reinforcing effect of spent catalysts and carbon blacks, in order to extend the reuse methods of spent catalysts and reduce the pollution caused by them to the environment. The experimental results demonstrated that the filler dispersion and distribution in the compound are more uniform after replacing the carbon black with modified spent FCC catalysts. The crosslinking density of rubber increases, the Payne effect is decreased, and the dynamic mechanical properties and aging resistance are improved. When the number of replacement parts reached 15, the comprehensive performance of the rubber composites remained the same as that of the control group. In this paper, the spent FCC catalysts modified by the physical method instead of the carbon-black-filled SBR can not only improve the performance of rubber products, but also can provide basic technical and theoretical support to realize the recycling of spent FCC catalysts and reduce the environmental pressure. The feasibility of preparing rubber composites by spent catalysts is also verified.
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spelling pubmed-99676602023-02-27 Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst Shan, Tilun Bian, Huiguang Zhu, Donglin Wang, Kongshuo Wang, Chuansheng Tian, Xiaolong Polymers (Basel) Article Spent Fluid Catalytic Cracking (FCC) Catalyst is a major waste in the field of the petroleum processing field, with a large output and serious pollution. The treatment cost of these waste catalysts is high, and how to achieve their efficient reuse has become a key topic of research at home and abroad. To this end, this paper conducted a mechanistic and experimental study on the replacement of some carbon blacks by spent FCC catalysts for the preparation of rubber products and explored the synergistic reinforcing effect of spent catalysts and carbon blacks, in order to extend the reuse methods of spent catalysts and reduce the pollution caused by them to the environment. The experimental results demonstrated that the filler dispersion and distribution in the compound are more uniform after replacing the carbon black with modified spent FCC catalysts. The crosslinking density of rubber increases, the Payne effect is decreased, and the dynamic mechanical properties and aging resistance are improved. When the number of replacement parts reached 15, the comprehensive performance of the rubber composites remained the same as that of the control group. In this paper, the spent FCC catalysts modified by the physical method instead of the carbon-black-filled SBR can not only improve the performance of rubber products, but also can provide basic technical and theoretical support to realize the recycling of spent FCC catalysts and reduce the environmental pressure. The feasibility of preparing rubber composites by spent catalysts is also verified. MDPI 2023-02-17 /pmc/articles/PMC9967660/ /pubmed/36850282 http://dx.doi.org/10.3390/polym15041000 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shan, Tilun
Bian, Huiguang
Zhu, Donglin
Wang, Kongshuo
Wang, Chuansheng
Tian, Xiaolong
Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title_full Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title_fullStr Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title_full_unstemmed Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title_short Study on the Mechanism and Experiment of Styrene Butadiene Rubber Reinforcement by Spent Fluid Catalytic Cracking Catalyst
title_sort study on the mechanism and experiment of styrene butadiene rubber reinforcement by spent fluid catalytic cracking catalyst
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9967660/
https://www.ncbi.nlm.nih.gov/pubmed/36850282
http://dx.doi.org/10.3390/polym15041000
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