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Atroposelective desymmetrization of 2-arylresorcinols via Tsuji-Trost allylation

Palladium-catalyzed asymmetric allylic alkylation has proven to be a powerful method for the preparation of a wide variety of chiral molecules. However, the catalytic and atroposelective allylic alkylation is still rare and challenging, especially for biaryl substrates. Herein, we report the palladi...

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Detalles Bibliográficos
Autores principales: Kim, Sangji, Kim, Aram, Lee, Chanhee, Moon, Junsoo, Hong, Eun Jeong, Lee, Duck-Hyung, Kwon, Yongseok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9968306/
https://www.ncbi.nlm.nih.gov/pubmed/36841918
http://dx.doi.org/10.1038/s42004-023-00839-z