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Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni(IV)[double bond, length as m-dash]O oxidant

The reaction of (NMe(4))(2)[Ni(II)(L(Ph))(OAc)] (1[OAc], L(Ph) = 2,2′,2′′-nitrilo-tris-(N-phenylacetamide); OAc = acetate) with 3-chloroperoxybenzoic acid (m-CPBA) resulted in the formation of a self-hydroxylated Ni(III)-phenolate complex, 2, where one of the phenyl groups of L(Ph) underwent hydroxy...

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Detalles Bibliográficos
Autores principales:	Heim, Philipp, Gericke, Robert, Spedalotto, Giuseppe, Lovisari, Marta, Farquhar, Erik R., McDonald, Aidan R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9972353/ https://www.ncbi.nlm.nih.gov/pubmed/36745393 http://dx.doi.org/10.1039/d2dt03949d

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