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Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides

Three high entropy materials (La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) coded as LTNWM1, LTNWM2, and LTNWM3 for X = B, Ga, and In) produced by aerodynamic containerless processing were evaluated for optical attributes, and their gamma-radiation absorption abilities were investigated in this report....

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Autores principales: Alzahrani, Jamila S., Alrowaili, Z.A., Eke, Canel, Altowyan, Abeer S., Olarinoye, I.O., Al-Buriahi, M.S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9975096/
https://www.ncbi.nlm.nih.gov/pubmed/36873158
http://dx.doi.org/10.1016/j.heliyon.2023.e13607
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author Alzahrani, Jamila S.
Alrowaili, Z.A.
Eke, Canel
Altowyan, Abeer S.
Olarinoye, I.O.
Al-Buriahi, M.S.
author_facet Alzahrani, Jamila S.
Alrowaili, Z.A.
Eke, Canel
Altowyan, Abeer S.
Olarinoye, I.O.
Al-Buriahi, M.S.
author_sort Alzahrani, Jamila S.
collection PubMed
description Three high entropy materials (La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) coded as LTNWM1, LTNWM2, and LTNWM3 for X = B, Ga, and In) produced by aerodynamic containerless processing were evaluated for optical attributes, and their gamma-radiation absorption abilities were investigated in this report. Optical related parameters such as the molar refractivity ([Formula: see text]), optical transmission ([Formula: see text]), molar polarizability ([Formula: see text]), metallization criterion ([Formula: see text]), reflection loss ([Formula: see text]), static ([Formula: see text]), and optical ([Formula: see text]) dielectric constants were estimated through standard expressions, while photon attenuation parameters were estimated from data from photon transmission simulations in FLUKA code and XCOM software. The attenuation parameters were calculated for a wide energy photon spectrum (15 keV–15 MeV). LTNWM1, LTNWM2, and LTNWM3 had [Formula: see text] values of 18.94 cm(3)/mol, 21.45 cm(3)/mol, and 26.09 cm(3)/mol respectively. The [Formula: see text] has a value of 7.52 × 10(−24) cm(3) for LTNWM1, 8.51 × 10(−24) cm(3) for LTNWM2, and 10.35 × 10(−24) cm(3) for LTNWM3. The photon shielding parameters evaluated by FLUKA and XCOM are compatible. The mass attenuation coefficient for the glasses was between 0.0338 and 52.8261 cm(2)/g, 0.0336–58.0237 cm(2)/g, and 0.0344–52.1560 cm(2)/g for LTNWM1, LTNWM2 and LTNWM3, respectively. The effective atomic number at 1.5 MeV was 18.718, 20.857, and 22.440 for LTNWM1, LTNWM2, and LTNWM3, respectively. The shielding parameters of the HMOs compared to traditional gamma radiation absorbers are exceptional and highlight the potential of using them as optically transparent gamma-shields.
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spelling pubmed-99750962023-03-02 Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides Alzahrani, Jamila S. Alrowaili, Z.A. Eke, Canel Altowyan, Abeer S. Olarinoye, I.O. Al-Buriahi, M.S. Heliyon Research Article Three high entropy materials (La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) coded as LTNWM1, LTNWM2, and LTNWM3 for X = B, Ga, and In) produced by aerodynamic containerless processing were evaluated for optical attributes, and their gamma-radiation absorption abilities were investigated in this report. Optical related parameters such as the molar refractivity ([Formula: see text]), optical transmission ([Formula: see text]), molar polarizability ([Formula: see text]), metallization criterion ([Formula: see text]), reflection loss ([Formula: see text]), static ([Formula: see text]), and optical ([Formula: see text]) dielectric constants were estimated through standard expressions, while photon attenuation parameters were estimated from data from photon transmission simulations in FLUKA code and XCOM software. The attenuation parameters were calculated for a wide energy photon spectrum (15 keV–15 MeV). LTNWM1, LTNWM2, and LTNWM3 had [Formula: see text] values of 18.94 cm(3)/mol, 21.45 cm(3)/mol, and 26.09 cm(3)/mol respectively. The [Formula: see text] has a value of 7.52 × 10(−24) cm(3) for LTNWM1, 8.51 × 10(−24) cm(3) for LTNWM2, and 10.35 × 10(−24) cm(3) for LTNWM3. The photon shielding parameters evaluated by FLUKA and XCOM are compatible. The mass attenuation coefficient for the glasses was between 0.0338 and 52.8261 cm(2)/g, 0.0336–58.0237 cm(2)/g, and 0.0344–52.1560 cm(2)/g for LTNWM1, LTNWM2 and LTNWM3, respectively. The effective atomic number at 1.5 MeV was 18.718, 20.857, and 22.440 for LTNWM1, LTNWM2, and LTNWM3, respectively. The shielding parameters of the HMOs compared to traditional gamma radiation absorbers are exceptional and highlight the potential of using them as optically transparent gamma-shields. Elsevier 2023-02-09 /pmc/articles/PMC9975096/ /pubmed/36873158 http://dx.doi.org/10.1016/j.heliyon.2023.e13607 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Alzahrani, Jamila S.
Alrowaili, Z.A.
Eke, Canel
Altowyan, Abeer S.
Olarinoye, I.O.
Al-Buriahi, M.S.
Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title_full Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title_fullStr Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title_full_unstemmed Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title_short Radiation shielding ability and optical features of La(2)O(3)+TiO(2)+Nb(2)O(5)+WO(3)+X(2)O(3) (X=B, Ga, and In) glass system containing high-entropy oxides
title_sort radiation shielding ability and optical features of la(2)o(3)+tio(2)+nb(2)o(5)+wo(3)+x(2)o(3) (x=b, ga, and in) glass system containing high-entropy oxides
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9975096/
https://www.ncbi.nlm.nih.gov/pubmed/36873158
http://dx.doi.org/10.1016/j.heliyon.2023.e13607
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