Dynamic effects on ligand field from rapid hydride motion in an iron(ii) dimer with an S = 3 ground state

Hydride complexes are important in catalysis and in iron–sulfur enzymes like nitrogenase, but the impact of hydride mobility on local iron spin states has been underexplored. We describe studies of a dimeric diiron(ii) hydride complex using X-ray and neutron crystallography, Mössbauer spectroscopy,...

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Detalles Bibliográficos
Autores principales: McWilliams, Sean F., Mercado, Brandon Q., MacLeod, K. Cory, Fataftah, Majed S., Tarrago, Maxime, Wang, Xiaoping, Bill, Eckhard, Ye, Shengfa, Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9977447/
https://www.ncbi.nlm.nih.gov/pubmed/36873832
http://dx.doi.org/10.1039/d2sc06412j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9977447/
https://www.ncbi.nlm.nih.gov/pubmed/36873832
http://dx.doi.org/10.1039/d2sc06412j

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