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Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion

[Image: see text] The explosion risk of ethylene (C(2)H(4)) seriously hinders safe development of its production and processing. To reduce the harm caused by C(2)H(4) explosion, an experimental study was conducted to assess the explosion inhibition characteristics of KHCO(3) and KH(2)PO(4) powders....

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Autores principales: Wang, Yang, Yang, JingJing, He, Jia, Wen, XiaoPing, Ji, WenTao, Wang, Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9979324/
https://www.ncbi.nlm.nih.gov/pubmed/36872980
http://dx.doi.org/10.1021/acsomega.2c06894
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author Wang, Yang
Yang, JingJing
He, Jia
Wen, XiaoPing
Ji, WenTao
Wang, Yan
author_facet Wang, Yang
Yang, JingJing
He, Jia
Wen, XiaoPing
Ji, WenTao
Wang, Yan
author_sort Wang, Yang
collection PubMed
description [Image: see text] The explosion risk of ethylene (C(2)H(4)) seriously hinders safe development of its production and processing. To reduce the harm caused by C(2)H(4) explosion, an experimental study was conducted to assess the explosion inhibition characteristics of KHCO(3) and KH(2)PO(4) powders. The experiments were conducted based on the explosion overpressure and flame propagation of the 6.5% C(2)H(4)–air mixture in a 5 L semi-closed explosion duct. Both the physical and chemical inhibition characteristics of the inhibitors were mechanistically assessed. The results showed that the 6.5% C(2)H(4) explosion pressure (P(ex)) decreases by increasing the concentration of KHCO(3) or KH(2)PO(4) powder. The inhibition effect of KHCO(3) powder on the C(2)H(4) system explosion pressure was better than that of the KH(2)PO(4) powder under similar concentration conditions. Both powders significantly affected the flame propagation of the C(2)H(4) explosion. Compared with KH(2)PO(4) powder, KHCO(3) powder had a better inhibition effect on the flame propagation speed, but its ability to reduce the flame luminance was less than KH(2)PO(4) powder. Finally, the inhibition mechanism(s) of KHCO(3) and KH(2)PO(4) powders were revealed based on the powders’ thermal characteristics and gas-phase reaction.
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spelling pubmed-99793242023-03-03 Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion Wang, Yang Yang, JingJing He, Jia Wen, XiaoPing Ji, WenTao Wang, Yan ACS Omega [Image: see text] The explosion risk of ethylene (C(2)H(4)) seriously hinders safe development of its production and processing. To reduce the harm caused by C(2)H(4) explosion, an experimental study was conducted to assess the explosion inhibition characteristics of KHCO(3) and KH(2)PO(4) powders. The experiments were conducted based on the explosion overpressure and flame propagation of the 6.5% C(2)H(4)–air mixture in a 5 L semi-closed explosion duct. Both the physical and chemical inhibition characteristics of the inhibitors were mechanistically assessed. The results showed that the 6.5% C(2)H(4) explosion pressure (P(ex)) decreases by increasing the concentration of KHCO(3) or KH(2)PO(4) powder. The inhibition effect of KHCO(3) powder on the C(2)H(4) system explosion pressure was better than that of the KH(2)PO(4) powder under similar concentration conditions. Both powders significantly affected the flame propagation of the C(2)H(4) explosion. Compared with KH(2)PO(4) powder, KHCO(3) powder had a better inhibition effect on the flame propagation speed, but its ability to reduce the flame luminance was less than KH(2)PO(4) powder. Finally, the inhibition mechanism(s) of KHCO(3) and KH(2)PO(4) powders were revealed based on the powders’ thermal characteristics and gas-phase reaction. American Chemical Society 2023-02-14 /pmc/articles/PMC9979324/ /pubmed/36872980 http://dx.doi.org/10.1021/acsomega.2c06894 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Wang, Yang
Yang, JingJing
He, Jia
Wen, XiaoPing
Ji, WenTao
Wang, Yan
Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title_full Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title_fullStr Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title_full_unstemmed Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title_short Inhibition Effect of KHCO(3) and KH(2)PO(4) on Ethylene Explosion
title_sort inhibition effect of khco(3) and kh(2)po(4) on ethylene explosion
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9979324/
https://www.ncbi.nlm.nih.gov/pubmed/36872980
http://dx.doi.org/10.1021/acsomega.2c06894
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