Origin of the Unusual Ground-State Spin S = 9 in a Cr(10) Single-Molecule Magnet

[Image: see text] The molecular wheel [Cr(10)(OMe)(20)(O(2)CCMe(3))(10)], abbreviated {Cr(10)}, with an unusual intermediate total spin S = 9 and non-negligible cluster anisotropy, D/k(B) = −0.045(2) K, is a rare case among wheels based on an even number of 3d-metals, which usually present an antife...

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Detalles Bibliográficos
Autores principales: Rubín, Javier, Arauzo, Ana, Bartolomé, Elena, Sedona, Francesco, Rancan, Marzio, Armelao, Lidia, Luzón, Javier, Guidi, Tatiana, Garlatti, Elena, Wilhelm, Fabrice, Rogalev, Andrei, Amann, Andreas, Spagna, Stefano, Bartolomé, Juan, Bartolomé, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9979690/
https://www.ncbi.nlm.nih.gov/pubmed/35759747
http://dx.doi.org/10.1021/jacs.2c05453

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9979690/
https://www.ncbi.nlm.nih.gov/pubmed/35759747
http://dx.doi.org/10.1021/jacs.2c05453

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