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Origin of the Unusual Ground-State Spin S = 9 in a Cr(10) Single-Molecule Magnet
[Image: see text] The molecular wheel [Cr(10)(OMe)(20)(O(2)CCMe(3))(10)], abbreviated {Cr(10)}, with an unusual intermediate total spin S = 9 and non-negligible cluster anisotropy, D/k(B) = −0.045(2) K, is a rare case among wheels based on an even number of 3d-metals, which usually present an antife...
| Autores principales: | , , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9979690/ https://www.ncbi.nlm.nih.gov/pubmed/35759747 http://dx.doi.org/10.1021/jacs.2c05453 |