Highly sensitive photoacoustic acetylene detection based on differential photoacoustic cell with retro-reflection-cavity

In this paper, a highly sensitive photoacoustic spectroscopy (PAS) sensor based on retro-reflection-cavity-enhanced differential photoacoustic cell (DPAC) is demonstrated for the first time. Acetylene (C(2)H(2)) was selected as the analyte. The DPAC was designed to effectively suppress noise and increase signal level. The retro-reflection-cavity consisted of two right-angle prisms was designed to reflect the incident light to realize four passes. The photoacoustic response of the DPAC was simulated and investigated based on the finite element method. Wavelength modulation and second harmonic demodulation technologies were applied for sensitive trace gas detection. The first-order resonant frequency of the DPAC was found to be 1310 Hz. The differential characteristics were investigated and the 2f signal amplitude for this C(2)H(2)-PAS sensor based on retro-reflection-cavity-enhanced DPAC had a 3.55 times improvement compared to the system without the retro-reflection-cavity. An Allan deviation analysis was performed to investigate the long-term stability of the system. The minimum detection limit (MDL) was measured to be 15.81 ppb with an integration time of 100 s