Tailoring Enhanced Elasticity of Crystalline Coordination Polymers

[Image: see text] The approach for enhancing the elasticity of crystals with suboptimal elastic performances through a rational design was presented. A hydrogen-bonding link was identified as a critical feature in the structure of the parent material, the Cd(II) coordination polymer [CdI(2)(I-pz)(2)...

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Autores principales: Mišura, Ozana, Pisačić, Mateja, Borovina, Mladen, Đaković, Marijana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9983303/
https://www.ncbi.nlm.nih.gov/pubmed/36879768
http://dx.doi.org/10.1021/acs.cgd.2c01397
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author Mišura, Ozana
Pisačić, Mateja
Borovina, Mladen
Đaković, Marijana
author_facet Mišura, Ozana
Pisačić, Mateja
Borovina, Mladen
Đaković, Marijana
author_sort Mišura, Ozana
collection PubMed
description [Image: see text] The approach for enhancing the elasticity of crystals with suboptimal elastic performances through a rational design was presented. A hydrogen-bonding link was identified as a critical feature in the structure of the parent material, the Cd(II) coordination polymer [CdI(2)(I-pz)(2)](n) (I-pz = iodopyrazine), to determine the mechanical output and was modified via cocrystallization. Small organic coformers resembling the initial organic ligand but with readily available hydrogens were selected to improve the identified link, and the extent of strengthening the critical link was in an excellent correlation with the delivered enhancement of elastic flexibility materials.
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spelling pubmed-99833032023-03-04 Tailoring Enhanced Elasticity of Crystalline Coordination Polymers Mišura, Ozana Pisačić, Mateja Borovina, Mladen Đaković, Marijana Cryst Growth Des [Image: see text] The approach for enhancing the elasticity of crystals with suboptimal elastic performances through a rational design was presented. A hydrogen-bonding link was identified as a critical feature in the structure of the parent material, the Cd(II) coordination polymer [CdI(2)(I-pz)(2)](n) (I-pz = iodopyrazine), to determine the mechanical output and was modified via cocrystallization. Small organic coformers resembling the initial organic ligand but with readily available hydrogens were selected to improve the identified link, and the extent of strengthening the critical link was in an excellent correlation with the delivered enhancement of elastic flexibility materials. American Chemical Society 2023-02-13 /pmc/articles/PMC9983303/ /pubmed/36879768 http://dx.doi.org/10.1021/acs.cgd.2c01397 Text en © 2023 American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Mišura, Ozana
Pisačić, Mateja
Borovina, Mladen
Đaković, Marijana
Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title_full Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title_fullStr Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title_full_unstemmed Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title_short Tailoring Enhanced Elasticity of Crystalline Coordination Polymers
title_sort tailoring enhanced elasticity of crystalline coordination polymers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9983303/
https://www.ncbi.nlm.nih.gov/pubmed/36879768
http://dx.doi.org/10.1021/acs.cgd.2c01397
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AT pisacicmateja tailoringenhancedelasticityofcrystallinecoordinationpolymers
AT borovinamladen tailoringenhancedelasticityofcrystallinecoordinationpolymers
AT đakovicmarijana tailoringenhancedelasticityofcrystallinecoordinationpolymers

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