Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst

Herein, the direct synthesis of polypyrrole (PPy)-coated palladium nanoparticles (PdNPs) inside a metal–organic framework (MIL-101) was successfully demonstrated. Owing to the PPy coating of PdNPs, the resulting composites exhibited higher semihydrogenation capability (selectivity: up to 96%) than t...

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Autores principales: Takashima, Yohei, Tetsusashi, Seiko, Tanaka, Shintaro, Tsuruoka, Takaaki, Akamatsu, Kensuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993127/
https://www.ncbi.nlm.nih.gov/pubmed/36908529
http://dx.doi.org/10.1039/d2ra08190c
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author Takashima, Yohei
Tetsusashi, Seiko
Tanaka, Shintaro
Tsuruoka, Takaaki
Akamatsu, Kensuke
author_facet Takashima, Yohei
Tetsusashi, Seiko
Tanaka, Shintaro
Tsuruoka, Takaaki
Akamatsu, Kensuke
author_sort Takashima, Yohei
collection PubMed
description Herein, the direct synthesis of polypyrrole (PPy)-coated palladium nanoparticles (PdNPs) inside a metal–organic framework (MIL-101) was successfully demonstrated. Owing to the PPy coating of PdNPs, the resulting composites exhibited higher semihydrogenation capability (selectivity: up to 96%) than the analog composite without PPy coating.
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spelling pubmed-99931272023-03-09 Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst Takashima, Yohei Tetsusashi, Seiko Tanaka, Shintaro Tsuruoka, Takaaki Akamatsu, Kensuke RSC Adv Chemistry Herein, the direct synthesis of polypyrrole (PPy)-coated palladium nanoparticles (PdNPs) inside a metal–organic framework (MIL-101) was successfully demonstrated. Owing to the PPy coating of PdNPs, the resulting composites exhibited higher semihydrogenation capability (selectivity: up to 96%) than the analog composite without PPy coating. The Royal Society of Chemistry 2023-03-08 /pmc/articles/PMC9993127/ /pubmed/36908529 http://dx.doi.org/10.1039/d2ra08190c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Takashima, Yohei
Tetsusashi, Seiko
Tanaka, Shintaro
Tsuruoka, Takaaki
Akamatsu, Kensuke
Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title_full Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title_fullStr Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title_full_unstemmed Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title_short Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
title_sort direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993127/
https://www.ncbi.nlm.nih.gov/pubmed/36908529
http://dx.doi.org/10.1039/d2ra08190c
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