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Palladium-catalyzed addition of acylsilanes across alkynes via the activation of a C–Si bond
Palladium-catalyzed addition of a C–Si bond in acylsilanes across the triple bonds in an alkyne bearing a carbonyl group at one terminal is reported. The reaction proceeds with excellent regioselectivity, in which a silyl group is incorporated into the carbon α to the carbonyl group, allowing for st...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993849/ https://www.ncbi.nlm.nih.gov/pubmed/36908943 http://dx.doi.org/10.1039/d3sc00181d |