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(E)-N-Phenyl-N-(phenylcarbamoyl)-3-[propyl(trimethylsilyl)amino]acrylamide chloroform hemisolvate
The title compound, C(22)H(29)N(3)O(2)Si·0.5CHCl(3), crystallizes in the the triclinic space group P [Image: see text] with two host molecules and one chloroform molecule in the asymmetric unit. The core of the molecule consists of a urea unit bound to a 3-amino-acryloyl group. These units are a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993897/ https://www.ncbi.nlm.nih.gov/pubmed/36911080 http://dx.doi.org/10.1107/S2414314623001177 |
Sumario: | The title compound, C(22)H(29)N(3)O(2)Si·0.5CHCl(3), crystallizes in the the triclinic space group P [Image: see text] with two host molecules and one chloroform molecule in the asymmetric unit. The core of the molecule consists of a urea unit bound to a 3-amino-acryloyl group. These units are almost planar in both molecules [average deviation from plane of 0.05 (6) Å in molecule A and 0.04 (5) Å in molecule B]. The main difference between molecules A and B involves the dihedral angles of the phenyl groups. One phenyl ring makes dihedral angles of 71.14 (6)° (molecule A) and 82.81 (7)° (molecule B) with respect to the core (C(4)N(3)O(2)) of the molecule [14.56 (9)° (molecule A) and 5.7 (1)° (molecule B) for the other phenyl ring]. Another prominent feature is the intramolecular N—H⋯O hydrogen bond present in both crystallographically independent molecules. [Image: see text] |
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