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Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer

The racemic title compound, C(34)H(32)OS(2), comprises an atropisomeric binaphthyl di­thio­acetal substituted at the methyl­ene carbon atom with a chiral benzyl alcohol. The two naphthalene ring systems are additionally substituted at the 3,3′-position with isopropyl groups. The overall stereochemis...

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Detalles Bibliográficos
Autores principales: Beare, Neil, Painter, Gavin F., McAdam, C. John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993907/
https://www.ncbi.nlm.nih.gov/pubmed/36909995
http://dx.doi.org/10.1107/S2056989023001706
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author Beare, Neil
Painter, Gavin F.
McAdam, C. John
author_facet Beare, Neil
Painter, Gavin F.
McAdam, C. John
author_sort Beare, Neil
collection PubMed
description The racemic title compound, C(34)H(32)OS(2), comprises an atropisomeric binaphthyl di­thio­acetal substituted at the methyl­ene carbon atom with a chiral benzyl alcohol. The two naphthalene ring systems are additionally substituted at the 3,3′-position with isopropyl groups. The overall stereochemistry is defined as aS,R and aR,S. The hydroxyl group forms an intra­molecular O—H⋯S hydrogen bond to one of the sulfur atoms. The crystal structure contains weak C—H⋯π inter­actions that link the mol­ecules into extended arrays.
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spelling pubmed-99939072023-03-09 Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer Beare, Neil Painter, Gavin F. McAdam, C. John Acta Crystallogr E Crystallogr Commun Research Communications The racemic title compound, C(34)H(32)OS(2), comprises an atropisomeric binaphthyl di­thio­acetal substituted at the methyl­ene carbon atom with a chiral benzyl alcohol. The two naphthalene ring systems are additionally substituted at the 3,3′-position with isopropyl groups. The overall stereochemistry is defined as aS,R and aR,S. The hydroxyl group forms an intra­molecular O—H⋯S hydrogen bond to one of the sulfur atoms. The crystal structure contains weak C—H⋯π inter­actions that link the mol­ecules into extended arrays. International Union of Crystallography 2023-02-28 /pmc/articles/PMC9993907/ /pubmed/36909995 http://dx.doi.org/10.1107/S2056989023001706 Text en © Beare et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Beare, Neil
Painter, Gavin F.
McAdam, C. John
Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title_full Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title_fullStr Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title_full_unstemmed Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title_short Syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
title_sort syntheses and crystal structure of a (2,6-diiso­propyldi­naphtho­[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phen­yl)methanol atropisomer
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993907/
https://www.ncbi.nlm.nih.gov/pubmed/36909995
http://dx.doi.org/10.1107/S2056989023001706
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