Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate

The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h )-symmetric compound that occurs on a general position in non-centrosymmetric tetra­gonal P4(1)2(1)2 (No. 92) with ¼ eq of n-pentane (C(5)H(12)) as co-crystallite. Intra­ligand bond lengths show the di­thiol­ene ligands to be i...

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Detalles Bibliográficos
Autores principales: Das Gupta, Titir, Applebaum, Jack, Broussard, William, Mack, Carson, Wu, Che, Mague, Joel T., Donahue, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993911/
https://www.ncbi.nlm.nih.gov/pubmed/36910003
http://dx.doi.org/10.1107/S205698902300097X
Descripción
Sumario:The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h )-symmetric compound that occurs on a general position in non-centrosymmetric tetra­gonal P4(1)2(1)2 (No. 92) with ¼ eq of n-pentane (C(5)H(12)) as co-crystallite. Intra­ligand bond lengths show the di­thiol­ene ligands to be in their half-oxidized radical monoanionic form. Inter­molecular ( t )Bu-C—H⋯arene(centroid) and ( t )Bu-C—H⋯NiS(2)C(2 centroid) close contacts guide the packing arrangement for 1.

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