Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate

The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h )-symmetric compound that occurs on a general position in non-centrosymmetric tetra­gonal P4(1)2(1)2 (No. 92) with ¼ eq of n-pentane (C(5)H(12)) as co-crystallite. Intra­ligand bond lengths show the di­thiol­ene ligands to be i...

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Detalles Bibliográficos
Autores principales: Das Gupta, Titir, Applebaum, Jack, Broussard, William, Mack, Carson, Wu, Che, Mague, Joel T., Donahue, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993911/
https://www.ncbi.nlm.nih.gov/pubmed/36910003
http://dx.doi.org/10.1107/S205698902300097X
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author Das Gupta, Titir
Applebaum, Jack
Broussard, William
Mack, Carson
Wu, Che
Mague, Joel T.
Donahue, James P.
author_facet Das Gupta, Titir
Applebaum, Jack
Broussard, William
Mack, Carson
Wu, Che
Mague, Joel T.
Donahue, James P.
author_sort Das Gupta, Titir
collection PubMed
description The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h )-symmetric compound that occurs on a general position in non-centrosymmetric tetra­gonal P4(1)2(1)2 (No. 92) with ¼ eq of n-pentane (C(5)H(12)) as co-crystallite. Intra­ligand bond lengths show the di­thiol­ene ligands to be in their half-oxidized radical monoanionic form. Inter­molecular ( t )Bu-C—H⋯arene(centroid) and ( t )Bu-C—H⋯NiS(2)C(2 centroid) close contacts guide the packing arrangement for 1.
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spelling pubmed-99939112023-03-09 Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate Das Gupta, Titir Applebaum, Jack Broussard, William Mack, Carson Wu, Che Mague, Joel T. Donahue, James P. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h )-symmetric compound that occurs on a general position in non-centrosymmetric tetra­gonal P4(1)2(1)2 (No. 92) with ¼ eq of n-pentane (C(5)H(12)) as co-crystallite. Intra­ligand bond lengths show the di­thiol­ene ligands to be in their half-oxidized radical monoanionic form. Inter­molecular ( t )Bu-C—H⋯arene(centroid) and ( t )Bu-C—H⋯NiS(2)C(2 centroid) close contacts guide the packing arrangement for 1. International Union of Crystallography 2023-02-17 /pmc/articles/PMC9993911/ /pubmed/36910003 http://dx.doi.org/10.1107/S205698902300097X Text en © Das Gupta et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Das Gupta, Titir
Applebaum, Jack
Broussard, William
Mack, Carson
Wu, Che
Mague, Joel T.
Donahue, James P.
Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title_full Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title_fullStr Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title_full_unstemmed Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title_short Bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(II) pentane 0.25-solvate
title_sort bis[1,2-bis­(4-tert-butyl­phen­yl)ethyl­ene-1,2-di­thiol­ato(1−)]nickel(ii) pentane 0.25-solvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993911/
https://www.ncbi.nlm.nih.gov/pubmed/36910003
http://dx.doi.org/10.1107/S205698902300097X
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