Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex

Quadruple-bond dimolybdenum complexes provide invaluable insight into the two-electron bond, with structural chemistry providing a foundation for examination of bond properties. The synthesis and solid-state structure of the quadruple-bonded dimolybdenum(II) complex tetra­kis­(μ-4-methyl­benzoato-κ...

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Autores principales: Bass, Lillian Dawson, Lee, Jessie H., Lilygren, McKenzie C., Hartnett, Alaina C., Campbell, Brandon M., Morphet, Daniel R., Dogutan, Dilek K., Zheng, Shao-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993912/
https://www.ncbi.nlm.nih.gov/pubmed/36909986
http://dx.doi.org/10.1107/S2056989023001457
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author Bass, Lillian Dawson
Lee, Jessie H.
Lilygren, McKenzie C.
Hartnett, Alaina C.
Campbell, Brandon M.
Morphet, Daniel R.
Dogutan, Dilek K.
Zheng, Shao-Liang
author_facet Bass, Lillian Dawson
Lee, Jessie H.
Lilygren, McKenzie C.
Hartnett, Alaina C.
Campbell, Brandon M.
Morphet, Daniel R.
Dogutan, Dilek K.
Zheng, Shao-Liang
author_sort Bass, Lillian Dawson
collection PubMed
description Quadruple-bond dimolybdenum complexes provide invaluable insight into the two-electron bond, with structural chemistry providing a foundation for examination of bond properties. The synthesis and solid-state structure of the quadruple-bonded dimolybdenum(II) complex tetra­kis­(μ-4-methyl­benzoato-κ (2) O:O′)bis[(tetra­hydro­furan-κO)molybdenum(II)] tetra­hydro­furan disolvate, [Mo(2)(C(8)H(7)O(2))(4)(C(4)H(8)O)(2)]·2C(4)H(8)O, are presented. This complex crystallizes in a triclinic cell with low-symmetry space group P [Image: see text] . The dimolybdenum paddlewheel structure comprises four methyl­benzoate ligands and two axial THF ligands. The dimolybdenum bond distance of 2.1012 (4) Å is exemplary of this class of compounds.
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spelling pubmed-99939122023-03-09 Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex Bass, Lillian Dawson Lee, Jessie H. Lilygren, McKenzie C. Hartnett, Alaina C. Campbell, Brandon M. Morphet, Daniel R. Dogutan, Dilek K. Zheng, Shao-Liang Acta Crystallogr E Crystallogr Commun Research Communications Quadruple-bond dimolybdenum complexes provide invaluable insight into the two-electron bond, with structural chemistry providing a foundation for examination of bond properties. The synthesis and solid-state structure of the quadruple-bonded dimolybdenum(II) complex tetra­kis­(μ-4-methyl­benzoato-κ (2) O:O′)bis[(tetra­hydro­furan-κO)molybdenum(II)] tetra­hydro­furan disolvate, [Mo(2)(C(8)H(7)O(2))(4)(C(4)H(8)O)(2)]·2C(4)H(8)O, are presented. This complex crystallizes in a triclinic cell with low-symmetry space group P [Image: see text] . The dimolybdenum paddlewheel structure comprises four methyl­benzoate ligands and two axial THF ligands. The dimolybdenum bond distance of 2.1012 (4) Å is exemplary of this class of compounds. International Union of Crystallography 2023-02-28 /pmc/articles/PMC9993912/ /pubmed/36909986 http://dx.doi.org/10.1107/S2056989023001457 Text en © Bass et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bass, Lillian Dawson
Lee, Jessie H.
Lilygren, McKenzie C.
Hartnett, Alaina C.
Campbell, Brandon M.
Morphet, Daniel R.
Dogutan, Dilek K.
Zheng, Shao-Liang
Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title_full Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title_fullStr Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title_full_unstemmed Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title_short Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
title_sort crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993912/
https://www.ncbi.nlm.nih.gov/pubmed/36909986
http://dx.doi.org/10.1107/S2056989023001457
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