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Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2) N,N′]diaquanickel(II) dichloride
The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-aminoethyl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-aminoethyl)morpholine...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993921/ https://www.ncbi.nlm.nih.gov/pubmed/36909993 http://dx.doi.org/10.1107/S2056989023001470 |
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author | Chidambaranathan, Balasubramanian Sivaraj, Settu Vijayamathubalan, Pandy Selvakumar, Shanmugam |
author_facet | Chidambaranathan, Balasubramanian Sivaraj, Settu Vijayamathubalan, Pandy Selvakumar, Shanmugam |
author_sort | Chidambaranathan, Balasubramanian |
collection | PubMed |
description | The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-aminoethyl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-aminoethyl)morpholine ligand, one coordinated water molecule and one chloride ion outside the metal coordination sphere. The nickel ion is in a octahedral environment of the N(4)O(2) type, coordinating four N atoms from two 4-(2-aminoethyl)morpholine ligands and two trans-located O atoms from two water molecules. The morpholine ligand was found disordered over two positions with a site occupancy ratio of 0.708 (8):0.292 (8). The crystal structure is consolidated by N—H⋯Cl, N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. Hirshfeld surface analysis confirms that van der Waals interactions are prevalent in the crystal packing of the synthesized complex. |
format | Online Article Text |
id | pubmed-9993921 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-99939212023-03-09 Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2) N,N′]diaquanickel(II) dichloride Chidambaranathan, Balasubramanian Sivaraj, Settu Vijayamathubalan, Pandy Selvakumar, Shanmugam Acta Crystallogr E Crystallogr Commun Research Communications The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-aminoethyl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-aminoethyl)morpholine ligand, one coordinated water molecule and one chloride ion outside the metal coordination sphere. The nickel ion is in a octahedral environment of the N(4)O(2) type, coordinating four N atoms from two 4-(2-aminoethyl)morpholine ligands and two trans-located O atoms from two water molecules. The morpholine ligand was found disordered over two positions with a site occupancy ratio of 0.708 (8):0.292 (8). The crystal structure is consolidated by N—H⋯Cl, N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. Hirshfeld surface analysis confirms that van der Waals interactions are prevalent in the crystal packing of the synthesized complex. International Union of Crystallography 2023-02-23 /pmc/articles/PMC9993921/ /pubmed/36909993 http://dx.doi.org/10.1107/S2056989023001470 Text en © Chidambaranathan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Chidambaranathan, Balasubramanian Sivaraj, Settu Vijayamathubalan, Pandy Selvakumar, Shanmugam Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2) N,N′]diaquanickel(II) dichloride |
title | Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
N,N′]diaquanickel(II) dichloride |
title_full | Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
N,N′]diaquanickel(II) dichloride |
title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
N,N′]diaquanickel(II) dichloride |
title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
N,N′]diaquanickel(II) dichloride |
title_short | Synthesis, crystal structure and Hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
N,N′]diaquanickel(II) dichloride |
title_sort | synthesis, crystal structure and hirshfeld surface analysis of bis[4-(2-aminoethyl)morpholine-κ(2)
n,n′]diaquanickel(ii) dichloride |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993921/ https://www.ncbi.nlm.nih.gov/pubmed/36909993 http://dx.doi.org/10.1107/S2056989023001470 |
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