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Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride

The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-amino­eth­yl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-amino­eth­yl)morpholine...

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Autores principales: Chidambaranathan, Balasubramanian, Sivaraj, Settu, Vijayamathubalan, Pandy, Selvakumar, Shanmugam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993921/
https://www.ncbi.nlm.nih.gov/pubmed/36909993
http://dx.doi.org/10.1107/S2056989023001470
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author Chidambaranathan, Balasubramanian
Sivaraj, Settu
Vijayamathubalan, Pandy
Selvakumar, Shanmugam
author_facet Chidambaranathan, Balasubramanian
Sivaraj, Settu
Vijayamathubalan, Pandy
Selvakumar, Shanmugam
author_sort Chidambaranathan, Balasubramanian
collection PubMed
description The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-amino­eth­yl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-amino­eth­yl)morpholine ligand, one coordinated water mol­ecule and one chloride ion outside the metal coordination sphere. The nickel ion is in a octa­hedral environment of the N(4)O(2) type, coordinating four N atoms from two 4-(2-amino­eth­yl)morpholine ligands and two trans-located O atoms from two water mol­ecules. The morpholine ligand was found disordered over two positions with a site occupancy ratio of 0.708 (8):0.292 (8). The crystal structure is consolidated by N—H⋯Cl, N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. Hirshfeld surface analysis confirms that van der Waals inter­actions are prevalent in the crystal packing of the synthesized complex.
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spelling pubmed-99939212023-03-09 Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride Chidambaranathan, Balasubramanian Sivaraj, Settu Vijayamathubalan, Pandy Selvakumar, Shanmugam Acta Crystallogr E Crystallogr Commun Research Communications The title coordination compound, [Ni(C(6)H(14)N(2)O)(2)(H(2)O)(2)]Cl(2), was synthesized by mixing 4-(2-amino­eth­yl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni(II) cation (located on an inversion centre), one 4-(2-amino­eth­yl)morpholine ligand, one coordinated water mol­ecule and one chloride ion outside the metal coordination sphere. The nickel ion is in a octa­hedral environment of the N(4)O(2) type, coordinating four N atoms from two 4-(2-amino­eth­yl)morpholine ligands and two trans-located O atoms from two water mol­ecules. The morpholine ligand was found disordered over two positions with a site occupancy ratio of 0.708 (8):0.292 (8). The crystal structure is consolidated by N—H⋯Cl, N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. Hirshfeld surface analysis confirms that van der Waals inter­actions are prevalent in the crystal packing of the synthesized complex. International Union of Crystallography 2023-02-23 /pmc/articles/PMC9993921/ /pubmed/36909993 http://dx.doi.org/10.1107/S2056989023001470 Text en © Chidambaranathan et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chidambaranathan, Balasubramanian
Sivaraj, Settu
Vijayamathubalan, Pandy
Selvakumar, Shanmugam
Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title_full Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title_fullStr Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title_full_unstemmed Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title_short Synthesis, crystal structure and Hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) N,N′]di­aqua­nickel(II) dichloride
title_sort synthesis, crystal structure and hirshfeld surface analysis of bis­[4-(2-amino­eth­yl)morpholine-κ(2) n,n′]di­aqua­nickel(ii) dichloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9993921/
https://www.ncbi.nlm.nih.gov/pubmed/36909993
http://dx.doi.org/10.1107/S2056989023001470
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