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Nucleophilic Reactivity at a =CH Arm of a Lutidine-Based CNC/Rh System: Unusual Alkyne and CO(2) Activation
[Image: see text] Reaction of an amido pincer complex [(CNC)*Rh(CO)] (1) (CNC* is the deprotonated form of CNC) with carbon dioxide gave a neutral complex [(CNC-CO(2))(Mes)*Rh(CO)] (2), which is the result of a C–C bond-forming reaction between the deprotonated arm of the CNC* ligand and CO(2). The...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9994788/ https://www.ncbi.nlm.nih.gov/pubmed/35476902 http://dx.doi.org/10.1021/acs.inorgchem.2c00617 |