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Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction
Attractive technology for producing sustainable hydrogen with water electrolyzers was foreseen as one of the most promising ways to meet the increasing demands of renewable resources and electricity storage. Mainly used for the efficient generation of H(2), water electrolysis involving hydrogen evol...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9995511/ https://www.ncbi.nlm.nih.gov/pubmed/36909712 http://dx.doi.org/10.3389/fchem.2023.1129133 |
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author | Ahmed, Imtiaz Biswas, Rathindranath Sharma, Rohit Burman, Vishal Haldar, Krishna Kanta |
author_facet | Ahmed, Imtiaz Biswas, Rathindranath Sharma, Rohit Burman, Vishal Haldar, Krishna Kanta |
author_sort | Ahmed, Imtiaz |
collection | PubMed |
description | Attractive technology for producing sustainable hydrogen with water electrolyzers was foreseen as one of the most promising ways to meet the increasing demands of renewable resources and electricity storage. Mainly used for the efficient generation of H(2), water electrolysis involving hydrogen evolution reactions (HERs) depends on efficient and affordable electrocatalysts. Hydrogen is an effective fuel that can be produced by splitting water. Hence, the search for highly efficient HER catalysts is a major challenge as efficient hydrogen evolution catalysts are sought to replace catalysts such as platinum. Here, we describe a low-cost and highly effective electrocatalyst for the proper incorporation of the HER electrocatalyst with low overpotential, effective charge transfer kinetics, low Tafel slope, and good durability. By using a simple hydrothermal approach to produce Co(3)(PO(4))(2).8H(2)O/CNF, it is possible to attach Co(3)(PO(4))(2).8H(2)O to the surface of carbon nanofibers (CNFs), which also exhibit remarkable HER activity at an overpotential of 133 mV and produce a current density of 10 mA/cm(2) and a 48 mV/decade for the Tafel slope. Large electrochemical surface areas and easy charge transfer from Co(3)(PO(4))(2).8H(2)O to the electrode through conductive Co(3)(PO(4))(2).8H(2)O/CNF composites are the reasons for the improved performance of Co(3)(PO(4))(2).8H(2)O/CNF. |
format | Online Article Text |
id | pubmed-9995511 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-99955112023-03-10 Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction Ahmed, Imtiaz Biswas, Rathindranath Sharma, Rohit Burman, Vishal Haldar, Krishna Kanta Front Chem Chemistry Attractive technology for producing sustainable hydrogen with water electrolyzers was foreseen as one of the most promising ways to meet the increasing demands of renewable resources and electricity storage. Mainly used for the efficient generation of H(2), water electrolysis involving hydrogen evolution reactions (HERs) depends on efficient and affordable electrocatalysts. Hydrogen is an effective fuel that can be produced by splitting water. Hence, the search for highly efficient HER catalysts is a major challenge as efficient hydrogen evolution catalysts are sought to replace catalysts such as platinum. Here, we describe a low-cost and highly effective electrocatalyst for the proper incorporation of the HER electrocatalyst with low overpotential, effective charge transfer kinetics, low Tafel slope, and good durability. By using a simple hydrothermal approach to produce Co(3)(PO(4))(2).8H(2)O/CNF, it is possible to attach Co(3)(PO(4))(2).8H(2)O to the surface of carbon nanofibers (CNFs), which also exhibit remarkable HER activity at an overpotential of 133 mV and produce a current density of 10 mA/cm(2) and a 48 mV/decade for the Tafel slope. Large electrochemical surface areas and easy charge transfer from Co(3)(PO(4))(2).8H(2)O to the electrode through conductive Co(3)(PO(4))(2).8H(2)O/CNF composites are the reasons for the improved performance of Co(3)(PO(4))(2).8H(2)O/CNF. Frontiers Media S.A. 2023-02-23 /pmc/articles/PMC9995511/ /pubmed/36909712 http://dx.doi.org/10.3389/fchem.2023.1129133 Text en Copyright © 2023 Ahmed, Biswas, Sharma, Burman and Haldar. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Ahmed, Imtiaz Biswas, Rathindranath Sharma, Rohit Burman, Vishal Haldar, Krishna Kanta Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title | Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title_full | Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title_fullStr | Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title_full_unstemmed | Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title_short | Access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
title_sort | access to carbon nanofiber composite hydrated cobalt phosphate nanostructure as an efficient catalyst for the hydrogen evolution reaction |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9995511/ https://www.ncbi.nlm.nih.gov/pubmed/36909712 http://dx.doi.org/10.3389/fchem.2023.1129133 |
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