Cargando…

Co-catalyzed arylation of aldehydes and aryltrimethylgermanes

A novel cobalt-catalyzed protocol for the synthesis of carbinol derivatives and benzil derivatives has been developed. In the presence of CoI(2) as the catalyst and tmphen (3,4,7,8-tetramethyl-1,10-phenanthroline) as the ligand, the corresponding arylated products were obtained from the addition of...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Qiang, Zou, Xiao, Zhang, Ningqi, Liu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9999368/
https://www.ncbi.nlm.nih.gov/pubmed/36909747
http://dx.doi.org/10.1039/d3ra00836c
_version_ 1784903650466856960
author Zhang, Qiang
Zou, Xiao
Zhang, Ningqi
Liu, Bo
author_facet Zhang, Qiang
Zou, Xiao
Zhang, Ningqi
Liu, Bo
author_sort Zhang, Qiang
collection PubMed
description A novel cobalt-catalyzed protocol for the synthesis of carbinol derivatives and benzil derivatives has been developed. In the presence of CoI(2) as the catalyst and tmphen (3,4,7,8-tetramethyl-1,10-phenanthroline) as the ligand, the corresponding arylated products were obtained from the addition of aryltrimethylgermanes to aromatic aldehydes and arylglyoxals in moderate to excellent yields under air atmosphere.
format Online
Article
Text
id pubmed-9999368
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-99993682023-03-11 Co-catalyzed arylation of aldehydes and aryltrimethylgermanes Zhang, Qiang Zou, Xiao Zhang, Ningqi Liu, Bo RSC Adv Chemistry A novel cobalt-catalyzed protocol for the synthesis of carbinol derivatives and benzil derivatives has been developed. In the presence of CoI(2) as the catalyst and tmphen (3,4,7,8-tetramethyl-1,10-phenanthroline) as the ligand, the corresponding arylated products were obtained from the addition of aryltrimethylgermanes to aromatic aldehydes and arylglyoxals in moderate to excellent yields under air atmosphere. The Royal Society of Chemistry 2023-03-10 /pmc/articles/PMC9999368/ /pubmed/36909747 http://dx.doi.org/10.1039/d3ra00836c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Zhang, Qiang
Zou, Xiao
Zhang, Ningqi
Liu, Bo
Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title_full Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title_fullStr Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title_full_unstemmed Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title_short Co-catalyzed arylation of aldehydes and aryltrimethylgermanes
title_sort co-catalyzed arylation of aldehydes and aryltrimethylgermanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9999368/
https://www.ncbi.nlm.nih.gov/pubmed/36909747
http://dx.doi.org/10.1039/d3ra00836c
work_keys_str_mv AT zhangqiang cocatalyzedarylationofaldehydesandaryltrimethylgermanes
AT zouxiao cocatalyzedarylationofaldehydesandaryltrimethylgermanes
AT zhangningqi cocatalyzedarylationofaldehydesandaryltrimethylgermanes
AT liubo cocatalyzedarylationofaldehydesandaryltrimethylgermanes