Cargando…
Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids
[Image: see text] We describe the first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes evolved through a cyclopropanation process providing access to densely functionalized cyclopr...
Autores principales: | Palomo, Eric, Sharma, Akhilesh K., Wang, Zhaofeng, Jiang, Liyin, Maseras, Feliu, Suero, Marcos G. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9999426/ https://www.ncbi.nlm.nih.gov/pubmed/36812070 http://dx.doi.org/10.1021/jacs.3c00012 |
Ejemplares similares
-
Catalytic Synthesis
of Cyclopropenium Cations with
Rh-Carbynoids
por: Tu, Hang-Fei, et al.
Publicado: (2022) -
Carbyne and carbynoid structures
por: Heimann, Robert, et al.
Publicado: (1999) -
Two
Copper-Carbenes from One Diazo Compound
por: Álvarez, María, et al.
Publicado: (2021) -
On the mechanism of imine elimination from Fischer tungsten carbene complexes
por: Veit, Philipp, et al.
Publicado: (2016) -
STUDIES ON BLOOD FACTORS Rh(A), Rh(B), AND Rh(C)
por: Unger, Lester J., et al.
Publicado: (1959)