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1por Cleaves, Peter A, King, David M, Kefalidis, Christos E, Maron, Laurent, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T“…Two-electron reductive carbonylation of the uranium(VI) nitride [U(Tren(TIPS))(N)] (2, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)) with CO gave the uranium(IV) cyanate [U(Tren(TIPS))(NCO)] (3). …”
Publicado 2014
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2por King, David M., McMaster, Jonathan, Tuna, Floriana, McInnes, Eric J. L., Lewis, William, Blake, Alexander J., Liddle, Stephen T.“…[Image: see text] Deprotonation of [U(Tren(TIPS))(NH(2))] (1) [Tren(TIPS) = N(CH(2)CH(2)NSiPr(i)(3))(3)] with organoalkali metal reagents MR (M = Li, R = Bu(t); M = Na–Cs, R = CH(2)C(6)H(5)) afforded the imido-bridged dimers [{U(Tren(TIPS))(μ-N[H]M)}(2)] [M = Li–Cs (2a–e)]. …”
Publicado 2014
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3por Gardner, Benedict M, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T“…Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo-P(5) complex [{U(Tren(TIPS))}(2)(μ-η(5):η(5)-cyclo-P(5))] (2). …”
Publicado 2015
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4por Gardner, Benedict M., Tuna, Floriana, McInnes, Eric J. L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T.“…Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo‐P(5) complex [{U(Tren(TIPS))}(2)(μ‐η(5):η(5)‐cyclo‐P(5))] (2). …”
Publicado 2015
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5por Gardner, Benedict M., Balázs, Gábor, Scheer, Manfred, Wooles, Ashley J., Tuna, Floriana, McInnes, Eric J. L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T.“…After two centuries of inconclusive or disproven claims of HAsAsH formation in the condensed phase, we report the isolation and structural authentication of HAsAsH in the diuranium(IV) complex [{U(Tren(TIPS))}(2)(μ‐η(2):η(2)‐As(2)H(2))] (3, Tren(TIPS)=N(CH(2)CH(2)NSiPr(i) (3))(3); Pr(i)=CH(CH(3))(2)). …”
Publicado 2015
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6por Gardner, Benedict M, Balázs, Gábor, Scheer, Manfred, Wooles, Ashley J, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T“…After two centuries of inconclusive or disproven claims of HAsAsH formation in the condensed phase, we report the isolation and structural authentication of HAsAsH in the diuranium(IV) complex [{U(Tren(TIPS))}(2)(μ-η(2):η(2)-As(2)H(2))] (3, Tren(TIPS)=N(CH(2)CH(2)NSiPr(i)(3))(3); Pr(i)=CH(CH(3))(2)). …”
Publicado 2015
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