“…The metal binding preferences of most metalloproteins do not match their metal requirements. …”
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“…In this paper, the synthesis of metal nanocrystals is reviewed. An introduction is briefly given to the metal nanocrystals and the importance of synthesis, and then commonly used synthesis methods for metallic nanocrystals are summarized, followed by specific examples of metal nanocrystals including noble metals, alloys, and base metals. …”
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“…In this paper, we describe magnetoelectric properties of metal/metal-oxide/metal junctions based on anodized metal oxides. …”
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“…Here, we review the use of metal ions and particles to catalyze the formation of hydrochars and related hybrid materials. …”
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“…[Image: see text] Understanding the fundamental properties governing metal–metal interactions is crucial to understanding the electronic structure and thereby applications of multimetallic systems in catalysis, material science, and magnetism. …”
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“…BACKGROUND: Metal-on-metal implants are a special form of hip endoprostheses that despite many advantages can entail serious complications due to release of wear particles from the implanted material. …”
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“…A postsynthetic, solid-state approach that reduces crystallization temperature in metal oxides is metal-induced crystallization (MIC). …”
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“…We developed synthetic methods for the doping of metals (M) with metallic nanoparticles (NPs). To the best of our knowledge – unlike oxides, polymers and carbon-based supports – metals were not used so far as supporting matrices for metallic NPs. …”
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“…In soil metal ecotoxicology research, dosing is usually performed with metal salts, followed by leaching to remove excess salinity. …”
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“…The existence of hybridization in the bonding between closed shell d(10)–d(10) metal atoms has also been speculated, but the presence of attractive MO interaction in the metal–metal bond is still a matter of an ongoing debate. …”
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“…In this study, we investigated the virucidal potential of different metal salts, metal and ceramic powders doped with Ag and Cu ions, and newly fabricated ceramic and metal surfaces against Phi6 bacteriophage. …”
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“…[Image: see text] Chiral transition metal catalysts represent a powerful and economic tool for implementing stereocenters in organic synthesis, with the metal center providing a strong chemical activation upon its interaction with substrates or reagents, while the overall chirality of the metal complex achieves the desired stereoselectivity. …”
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“…The fact that metal-binding proteins are a consequence of elevated metal concentration in organisms is well known. …”
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“…Metallic elements, ions and compounds produce varying degrees of toxicity in organisms with which they come into contact. …”
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“…Metal–organic frameworks (MOFs) are crystalline porous materials composed of metal ions or clusters coordinated with organic linkers. …”
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“…The second oxidation of the complexes was shown to take place at the metal left unaffected in the first redox step. Finally, the tipping point could be realized in the unlike isomer of the electronically tuned thiophenolate congener [Tp′(CO)(PhS)W{μ‐η(2)‐C,C′‐κ(2)‐S,P‐C(2)(PPh(2))S}Ru(η(5)‐C(5)H(5))‐(PPh(3))], in which valence trapped W(III)/Ru(II) and W(II)/Ru(III) cationic species are at equilibrium.…”
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“…Here, we show that some metal ions, such as silver, strontium, cerium ions, which exist in the precursors of halide perovskites as impurities, can n-dope the surface of perovskites from being intrinsic to metallic. …”
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“…Till now, this simple correlation, basic in the bond valence model (BVM), is widely used in crystal chemistry, but it was considered irrelevant for metal–metal bonds. An extensive analysis of the quantum chemistry data computed in the last years confirms very well the validity of Pauling’s correlation for both localized and delocalized interactions. …”
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