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“…The rings of the central [3.3]MCP unit are not parallel, but orientated at a slight angle of 2.66 (9)°. …”
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“…Interestingly, the G34 mutations, the K36M mutations, and the majority of K27M mutations occur in genes encoding the replacement histone H3.3. Here, we review the peculiar characteristics of histone H3.3 and use this information as a backdrop to highlight current thinking about how the identified mutations may contribute to disease development.…”
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“…A novel isocyanide-based multicomponent synthesis of alkyl aryl(indol-3-yl)acetimidates has been established. Starting from aryl(indol-3-yl)methylium tetrafluoroborates, aromatic isocyanides and alcohols, the imidates were obtained in moderate to very good yields. …”
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“…The three isomorphous [3.3.1] metallacryptate complexes bis­(pyridinium) di­aqua­dipyridine­hexa­kis­[μ(3)-salicyl­hydroximato(3−)]bis­[μ(2)-salicyl­hydroxim­ato(1−)]hexa­aluminiumgadolinium–pyridine–water (1/7.396/1), (C(5)H(6)N)(2)[GdAl(6)(C(7)H(6)NO(3))(2)(C(7)H(4)NO(3))(7)(C(5)H(5)N)(1.855)(H(2)O)(2)]·7.396C(5)H(5)N·H(2)O or [Hpy](2)[GdAl(6)(H(2)shi)(2)(shi)(7)(py)(1.855)(H(2)O)(2)]·7.396py·H(2)O, 1, bis­(pyridinium) di­aqua­dipyridine­hexa­kis­[μ(3)-salicyl­hydroximato(3−)]bis­[μ(2)-salicyl­hydroxim­ato(1−)]hexa­aluminiumdysprosium–pyridine–water (1/7.429/1), (C(5)H(6)N)(2)[DyAl(6)(C(7)H(6)NO(3))(2)(C(7)H(4)NO(3))(7)(C(5)H(5)N)(1.855)(H(2)O)(2)]·7.429C(5)H(5)N·H(2)O or [Hpy](2)[DyAl(6)(H(2)shi)(2)(shi)(7)(py)(1.891)(H(2)O)(2)]·7.429py·H(2)O, 2, and bis­(pyrid­in­ium) di­aqua­dipyridine­hexa­kis­[μ(3)-salicyl­hydroximato(3−)]bis­[μ(2)-salicyl­hydrox­imato(1−)]hexa­aluminiumytterbium–pyridine–water (1/7.386/1), (C(5)H(6)N)(2)[YbAl(6)(C(7)H(6)NO(3))(2)(C(7)H(4)NO(3))(7)(C(5)H(5)N)(1.855)(H(2)O)(2)]·7.429C(5)H(5)N·H(2)O or [Hpy](2)[YbAl(6)(H(2)shi)(2)(shi)(7)(py)(1.818)(H(2)O)(2)]·7.386py·H(2)O, 3, where Hpy(+) is pyridinium, shi(3−) is salicyl­hydroximate, and py is pyridine, consist of an aluminium-based metallacryptand that captures an Ln (III) ion in the central cavity. …”
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“…In this work, gelatin methacrylate (GelMA)/alginate hydrogel scaffolds were obtained by 3D printing and 14-3-3ε protein was encapsulated in the hydrogel to induce osteogenic differentiation of human adipose-derived mesenchymal stem cells (hASC). …”
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“…A multicomponent reaction of isocyanides with aryl(indol-3-yl)methylium salts and amines has been found. …”
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“…Here, we have synthesized highly crystalline Er(3+), Yb(3+) co-doped upconverting KGd(3)F(10) nanoparticles (NPs) by the EDTA-assisted hydrothermal method. …”
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“…We report our experience with needlescopic splenectomy (NS) for the surgical treatment of idiopathic thrombocytopenic purpura using a 3-mm needlescope with three ports. One patient was male and two were females, and their mean age was 58 years. …”
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“…We describe the total flow synthesis of the widely prescribed anti-inflammatory COX-2 inhibitor Celecoxib from 2-bromo-3,3,3-trifluoropropene, as a convenient and available trifluoromethyl building block, to generate trifluoropropynyl lithium and to trap it immediately with an aldehyde. …”
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“…The CH(3)NH(3)PbI(3) (MAPbI(3)) powders were ground by PbI(2) and CH(3)NH(3)I prepared by ice bath method. …”
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“…We recently identified two intrinsic Janus kinase (JAK) inhibitors, JAK binding protein (JAB; also referred to as suppressor of cytokine signaling [SOCS1]/STAT-induced STAT inhibitor [SSI1]) and cytokine-inducible SH2 protein (CIS)3 (or SOCS3/SSI3), which play an essential role in the negative regulation of cytokine signaling. …”
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“…The compound exists in a twin-chair conformation with equatorial dispositions of the 3-bromo­phenyl groups [dihedral angle between rings = 27.37 (3)°]. …”
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“…The title compound, C(20)H(19)F(2)NO, exhibits a chair–chair conformation, with the aryl groups in the heterocycle in equatorial orientations and oriented at an angle of 33.35 (3)° to one another. A crystallographic mirror plane, passing through the N atom, the C and O atoms of the carbonyl group and the C atom in the 7-position, bis­ects the mol­ecule. …”
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“…The title mol­ecule, C(11)H(12)N(2)O(4), consists of a 3-aza­bicyclo­[3.2.0]heptane group containing a nearly planar cyclo­butane ring (r.m.s. deviation of fitted atoms is 0.0609 Å), fused to a pyrrolidine ring, bonded to a 2,6-dioxopiperidine ring at the 3-position. …”
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“…The title compound is a positional isomer of 2,4-bis­(2-methoxy­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one and 2,4-bis­(4-methoxy­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one, which both also exhibit twin-chair conformations with equatorial dispositions of the anisyl rings on both sides of the secondary amino group. …”
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