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  1. 7221
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    The oxygen framework in garnet and its occurrence in the structures of Na$_{3}$Al$_{2}$Li$_{3}$F$_{12}$, Ca$_{3}$Al$_{2}$(OH)$_{12}$, RhBi$_{4}$ and Hg$_{3}$TeO$_{6}$
  2. 7222
    “…OBJECTIVE: This study compared the dynamic susceptibility contrast (DSC) magnetic resonance imaging parameters and apparent diffusion coefficient (ADC) between pilocytic astrocytoma (PA) and diffuse midline glioma, H3K27-altered (DMG) variants. METHODS: The normalized relative cerebral blood volume (nrCBV), normalized relative flow (nrCBF), percentile signal recovery (PSR), and normalized mean ADC (nADCmean) of 23 patients with midline PAs (median age, 13 years [range, 1–71 years]; 13 female patients) and 40 patients with DMG (8.5 years [1–35 years]; 19 female patients), including 35 patients with H3.3- and five patients with H3.1-mutant tumors, treated between January 2016 and May 2022 were statistically compared. …”
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    Dynamic susceptibility contrast perfusion-weighted and diffusion-weighted magnetic resonance imaging findings in pilocytic astrocytoma and H3.3 and H3.1 variant diffuse midline glioma, H3K27-altered
  3. 7223
    “…In this study, red-emitting Eu(3+)-doped Gd(BO(2))(3)-Y(3)BO(6)-GdBO(3) (GdYGd:Eu(3+)) phosphor with a high quantum efficiency of 58.4% and excellent color purity of 99.5% is reported for the first time. …”
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    High quantum efficiency and excellent color purity of red-emitting Eu(3+)-heavily doped Gd(BO(2))(3)-Y(3)BO(6)-GdBO(3) phosphors for NUV-pumped WLED applications
  4. 7224
    “…A facile and efficient method has been developed for the synthesis of C3-difluoromethyl carbinol-containing imidazo[1,2-a]pyridines at room temperature via the HFIP-promoted Friedel–Crafts reaction of difluoroacetaldehyde ethyl hemiacetal and imidazo[1,2-a]pyridines. …”
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    1,1,1,3,3,3-Hexafluoro-2-Propanol-Promoted Friedel–Crafts Reaction: Metal-Free Synthesis of C3-Difluoromethyl Carbinol-Containing Imidazo[1,2-a]pyridines at Room Temperature
  5. 7225
    por Northrop, John H., Kunitz, M.
    Publicado 1928
    “…No calcium is combined on the acid side of pH 3. The value rises rapidly from pH 3 to 4.7 and then remains constant. 5. …”
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    COMBINATION OF SALTS AND PROTEINS : III. THE COMBINATION OF CuCl(2), MgCl(2), CaCl(2), AlCl(3), LaCl(3), KCl, AgNO(3)AND Na(2)SO(4)WITH GELATIN.
  6. 7226
    “…The 1,3-benzodioxole ring systems in the title compound, C(22)H(22)O(8), are almost planar. …”
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    4-Meth­oxy-5-[4-(4-meth­oxy-1,3-benzodioxol-5-yl)perhydro-1H,3H-furo[3,4-c]furan-1-yl]-1,3-benzodioxole
  7. 7227
    “…The title compound, C(26)H(38)O(3), was prepared by an intra­molecular Claisen-like cyclization of ethyl 2-acet­oxy-4,4-dimethyl-1-(3-methyl­but-2-en­yl)cyclo­hex-2-enecarboxyl­ate followed by dialkyl­ation. …”
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    7,7-Dimethyl-3,3,4a-tris­(3-methyl­but-2-en­yl)-4a,5,6,7-tetra­hydro-2H-chromene-2,4(3H)-dione
  8. 7228
    “…The asymmetric unit of the title complex, [Ni(2)(C(16)H(6)O(8))(C(10)H(8)N(2))(2)(H(2)O)(6)]·6H(2)O, contains one Ni(II) atom, one 2,2′-bipyridine ligand, three coordinated water mol­ecules, one-half of a fully deprotonated biphenyl-3,3′,4,4′-tetra­carboxyl­ate anion and three lattice water mol­ecules. …”
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    μ-Biphenyl-3,3′,4,4′-tetra­carboxyl­ato-κ(2) O (3):O (3′)-bis­[triaqua­(2,2′-bipyridyl-κ(2) N,N′)nickel(II)] hexa­hydrate
  9. 7229
    “…These chains are connected via π–π inter­actions [centroid–centroid = 3.7523 (13) Å].…”
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    Ethyl 2-(2-acetoxy­benzyl­idene)-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
  10. 7230
    “…In the title compound, C(18)H(19)N(3)O(5), the 3,6-dihydro-2H-pyran ring adopts a half-chair, distorted towards a half-boat, conformation with Q (T) = 0.5276(14) Å. …”
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    [(2R,3S,6S)-3-Acet­yloxy-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-3,6-dihydro-2H-pyran-2-yl]methyl acetate
  11. 7231
    “…In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy­droxy­isophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octa­hedral geometry. …”
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    Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hy­droxy­isophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium]
  12. 7232
    “…In the title compound, C(21)H(21)N(3)O(3), the relative stereochemistry of the four stereogenic C atoms has been determined. …”
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    2-[(1RS,3RS,3aRS,6aSR)-5-Benzyl-4,6-dioxo-3-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrol-1-yl]acetamide
  13. 7233
    “…In the title compound, C(17)H(16)ClN(3)O(2)S, the dihedral angle between the benzene rings is 7.75 (13)°. …”
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    (3S,4Z)-3-Chloro-1-methyl-4-[(2E)-(3-methyl­benzyl­idene)hydrazinyl­idene]-3,4-dihydro-1H-2,1-benzothia­zine 2,2-dioxide
  14. 7234
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    Methyl (2E)-2-({2-[(2E)-2-benzyl­idene-3-meth­oxy-3-oxoprop­yl]-1,3-dioxoindan-2-yl}meth­yl)-3-phenyl­prop-2-enoate
  15. 7235
    “…In the 3,3′-diethyl-1,1′-(propane-1,3-di­yl)di(1H-imidazol-3-ium) cation, the dihedral angle between the imidazole rings is 49.3 (1)°. …”
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    catena-Poly[3,3′-diethyl-1,1′-(propane-1,3-di­yl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]]
  16. 7236
    “…In the crystal, mol­ecules are consolidated into a three-dimensional architecture by C—H⋯O inter­actions, involving all three carbonyl-O atoms, and π–π inter­actions occurring between the pyrimidinyl and isoindole-benzene rings [inter-centroid distance = 3.5330 (13) Å].…”
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    2-(2-{[4-Oxo-3-(2-phenyl­eth­yl)-3,4-dihydro­quinazolin-2-yl]sulfan­yl}eth­yl)-2,3-dihydro-1H-isoindole-1,3-dione
  17. 7237
    “…The title compound, C(16)H(19)N(3)O(4)S, is almost planar, with a dihedral angle of 2.88 (9)° between the mean planes of the benzene and thia­zole rings. …”
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    Ethyl 2-[2-(4-hy­droxy-3-meth­oxy­benzyl­idene)hydrazin-1-yl­idene]-3,4-dimethyl-2,3-dihydro-1,3-thia­zole-5-carboxyl­ate
  18. 7238
    “…RESULTS: Two compounds, emodin and the novel flavan-3-ol, (−)-epiafzelechin-3-O-p-coumarate (rhodoeosein), were identified to be responsible for estrogenic activity of F. convolvulus seed extract. …”
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    2,3-cis-2R,3R-(−)-epiafzelechin-3-O-p-coumarate, a novel flavan-3-ol isolated from Fallopia convolvulus seed, is an estrogen receptor agonist in human cell lines
  19. 7239
    “…They stack along the a axis with π–π inter­actions involving the 4H-chromene units [centroid–centroid distances of 3.6389 (13) and 3.6555 (13) Å]. The terminal CH(2)=CH- atoms of the allyl acetate group are disordered over two sets of sites with a refined occupancy ratio of 0.717 (6):0.283 (6).…”
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    Allyl 2-(2,2-dimethyl-3a,6a-di­hydro­furo[3,2-d][1,3]dioxol-5-yl)-4-oxo-4H-chromene-3-carboxyl­ate
  20. 7240
    “…The crystal packing features C—H⋯O hydrogen bonds, forming a three-dimensional structure. The meth­oxy­carbonyl atoms are disordered over two positions, with a refined occupancy ratio of 0.508 (18):0.492 (18).…”
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    Methyl 2-(2,2-dimethyl-3a,6a-di­hydro­furo[3,2-d][1,3]dioxol-5-yl)-4-oxo-4H-chromene-3-carboxyl­ate
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