“…Our activation strain analyses reveal that the base accelerates the DA reaction via two distinct electronic mechanisms: i) by the HOMO‐raising effect, which enhances the normal electron demand orbital interaction; and ii) by donating charge into 3‐hydroxy‐2‐pyrone which accumulates in its reactive region and promotes strongly stabilizing secondary electrostatic interactions with N‐methylmaleimide.…”
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“…The most potent analogues are thermine, spermine, and 1,12-diaminododecane homo- and heterodimeric polyamine succinic acid amides. …”
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“…The list of differential diagnoses, based on our literature review, can be recalled with the mnemonic HEIGHT OF HOMO: H—Histiocytosis; E—Ewing’s sarcoma; I—Infection; G—Giant cell tumor; H—Hematologic neoplasms; T—Tuberculosis; O—Osteogenesis imperfecta; F—Fracture; H—Hemangioma; O—Osteoblastoma; M—Metastasis; O—Osteomyelitis, chronic.…”
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“…Activation of FPR1 by mtFPs enables PMN to reach the injury site; however, at the same time it leads to homo- and heterologous desensitization/internalization of chemokine receptors. …”
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“…The evolution of the genus Homo can only be understood by considering both of the inheritance systems that interact to shape human nature: biology and culture. …”
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“…Here we demonstrate that 1,3-dienes form electron-neutral and HOMO-raised η(2)-complexes with Pd(0) via π-Lewis base activation, which undergoes protonation with a variety of acidic sources, such as Brønsted acids, Lewis acid-activated indazoles, and Pd(ii) pre-catalyst triggered ammonium salts. …”
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“…The energy variations between HOMO and LUMO are utilised to calculate various energy parameters. …”
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“…Here, we investigate the phylogenetic diversity in the recognition and repair of three well-established DNA lesions, primarily repaired by base excision repair (BER) and ribonucleotide excision repair (RER): (1) 8-oxoguanine, (2) abasic site, and (3) incorporated ribonucleotide in DNA in 11 species: Escherichia coli, Bacillus subtilis, Halobacterium salinarum, Trypanosoma brucei, Tetrahymena thermophila, Saccharomyces cerevisiae, Schizosaccharomyces pombe, Caenorhabditis elegans, Homo sapiens, Arabidopsis thaliana, and Zea mays. …”
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“…The AMG–peptide hybrids were conjugated using the click chemistry reaction in solution to obtain a non-cleavable triazole linker and by disulfide bridge formation on the resin to obtain a linker cleavable in the bacterial cytoplasm. Homo-dimers connected via disulfide bridges between the N-terminus thiol analogues of anoplin and hydrocarbon stapled anoplin were also synthesized. …”
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“…Additional transitions are detected correlating to the forbidden (1)S → (1)D silver cation-based atomic resonance and to the HOMO–LUMO excitation on the benzene or toluene ligand. …”
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“…Herpes simplex virus-1 (HSV-1) and -2 (HSV-2) are large, spherically shaped, double-stranded DNA viruses that coevolved with Homo sapiens for over 300,000 years, having developed numerous immunoevasive mechanisms to survive the lifetime of their human host. …”
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“…All multicomponent solvate crystals encompass amide–amide dimer homo synthons and form R(2)(2) (8) motifs. Moreover, the phase purity of solvate crystals was analyzed by powder X-ray diffraction. …”
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“…Other mechanisms still largely unexplored, such as S-nitrosation of the AT(1) receptor, homo- and heterodimerization, and the use of AT(1) receptor-biased agonists, may significantly contribute to and/or interfere with the settings of this AT(1)/AT(2) equilibrium. …”
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“…When human populations emerged in these natural ecosystems, after the sedentarization of Homo sapiens, more or less important disturbances would have led to a transition of sand fly hematophagy, from zoophilia, to zoo-anthropophilia and anthropophilia. …”
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“…We attribute the enhanced photocatalysis to an efficient charge separation at the gold–polyvinylpyrrolidone interface, where photogenerated d-band holes at gold transfer to the HOMO of polyvinylpyrrolidone, leading to the prolonged lifetime of the electrons that subsequently reduce gold ions to gold atoms. …”
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“…Here, we combine phylogenetic analysis to profile SLC25 transporters across common eukaryotic model organisms, from Saccharomyces cerevisiae, Caenorhabditis elegans, Drosophila melanogaster, Danio rerio, to Homo sapiens, and assess their sequence adaptations to the transported ligands within individual subfamilies. …”
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“…Electron propagator theory calculations yield a HOMO–LUMO gap of 8.24 eV for H(2)S∙∙∙SO(2). Furthermore, by utilizing ab initio results for the adiabatic ionization energy and electron affinity, the electrophilicity of H(2)S∙∙∙SO(2) is estimated to be 2.01 eV. …”
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“…Here, we describe the synthesis of high-molecular-weight homo, block, and statistical polymers of azide-functionalized proline. …”
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“…In addition, the highest occupied molecular orbital (HOMO) energy level of PSEHTT is deeper than that of PM6, which broadens the optical bandgap. …”
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“…Previously, liposomes have been prepared using a homo mixer, microfluidizer, and horn and bath types of sonicators. …”
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