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121por Fujii, Yui, Yoritate, Makoto, Makino, Kana, Igawa, Kazunobu, Takeda, Daiki, Doiuchi, Daiki, Tomooka, Katsuhiko, Uchida, Tatsuya, Hirai, Go“…Seven mono- and dihydroxycholesterols were prepared by direct C–H oxidation of the cholestane skeleton with a recently developed Ru(Bpga) catalyst (Ru(Bpga) = [RuCl (bpga) (PPh(3))] Cl; bpga = 2-(bis(pyridin-2-ylmethyl)amino)-N-(2,6-dimethylphenyl)acetamide)). …”
Publicado 2021
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122“…A double-decker silsesquioxane based bis(terpyridine) ruthenium(ii) complex (2Tpy/Ru-DDSQ), a member of the polyhedral oligomeric silsesquioxane (POSS) class, has been synthesized. …”
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123por Du, Junyi, Huang, Yan, Huang, Zixiang, Wu, Geng, Wu, Bei, Han, Xiao, Chen, Cai, Zheng, Xusheng, Cui, Peixin, Wu, Yuen, Jiang, Jun, Hong, Xun“…Herein, the phase engineering of the support is adopted to control the chemo-recognition behavior of SACs in selective hydrogenation. Single-atom Ru on amorphous porous ultrathin TiO(2) nanosheets (Ru(1)/a-TiO(2)) is constructed, in which Ru is more positively charged than that in the crystalline counterpart (Ru(1)/c-TiO(2)). …”
Publicado 2022
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124por Han, Lili, Ou, Pengfei, Liu, Wei, Wang, Xiang, Wang, Hsiao-Tsu, Zhang, Rui, Pao, Chih-Wen, Liu, Xijun, Pong, Way-Faung, Song, Jun, Zhuang, Zhongbin, Mirkin, Michael V., Luo, Jun, Xin, Huolin L.“…In situ scanning electrochemical microscopy study validates the HOR activity resulting from the Ru-Ni diatomic sites. Furthermore, in situ x-ray absorption spectroscopy and computational studies unveil a synergistic interaction between Ru and Ni to promote the molecular H(2) dissociation and strengthen OH adsorption at the diatomic sites, and thus enhance the kinetics of HOR.…”
Publicado 2022
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125“…For [{Re[TpXPC]}(2)](0), [{Ru[TpXPC]}(2)](0), and [{Os[TpXPC]}(2)](0), CASSCF calculations shows that the effective bond order is 3.29, 2.63, and 2.73, respectively. …”
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126por Li, You-Sheng, Garst, Markus, Schmalian, Jörg, Ghosh, Sayak, Kikugawa, Naoki, Sokolov, Dmitry A., Hicks, Clifford W., Jerzembeck, Fabian, Ikeda, Matthias S., Hu, Zhenhai, Ramshaw, B. J., Rost, Andreas W., Nicklas, Michael, Mackenzie, Andrew P.“…The phase diagram is intriguing both for its similarity to those seen in other families of unconventional superconductors and for extra features unique, so far, to Sr(2)RuO(4).…”
Publicado 2022
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127por Liu, Albert K., Pereira, Jose H., Kehl, Alexander J., Rosenberg, Daniel J., Orr, Douglas J., Chu, Simon K. S., Banda, Douglas M., Hammel, Michal, Adams, Paul D., Siegel, Justin B., Shih, Patrick M.“…Here, we retrace the evolution of ancestral and extant form II RuBisCOs, revealing a complex and diverse history of oligomerization. …”
Publicado 2022
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128por Janssens, K., Bugaev, A. L., Kozyr, E. G., Lemmens, V., Guda, A. A., Usoltsev, O. A., Smolders, S., Soldatov, A. V., De Vos, D. E.“…In addition, in the absence of CO, the catalyst was reduced to Ru(0), and this was associated with a significant decrease of the selectivity for ketone hydrogenation. …”
Publicado 2022
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129por Holden, Lorcan, Gkika, Karmel S., Burke, Christopher S., Long, Conor, Keyes, Tia E.“…We report here, on a Ru(II) complex (Ru-PDC3) that assembles the light switch capability of a Ru(II) dipyridylphenazine complex with the well-known G4-selective ligand Phen-DC3, into a single structure. …”
Publicado 2023
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130por Bannenberg, Lars J., Schreuders, Herman, van Beugen, Nathan, Kinane, Christy, Hall, Stephen, Dam, Bernard“…Using a combination of optical transmission measurements, ex situ and in situ X-ray diffraction, and neutron and X-ray reflectometry, we show that introducing Ru in Ta results in a solid solution of Ta and Ru up to at least 30% Ru. …”
Publicado 2023
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131por Chakraborty, Arpon, Liton, M. N. H., Sarker, M. S. I., Rahman, M. M., Khan, M. K. R.“…The structural, dynamical, electro-optical, mechanical, and thermal characteristics of the newly synthesized intermetallic compounds Ru(4)Al(3)B(2) and Ru(9)Al(3)B(8) have been studied under ambient and elevated pressure through density functional theory (DFT). …”
Publicado 2023
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132por Witzel, Benedikt J. L., Klein, Wilhelm, Dums, Jasmin V., Boyko, Marina, Fässler, Thomas F.“…We report also on the structural characterization of [Co@Ge(9)](5−) (1a) and [Ru@Sn(9)](6−) (2a) obtained from solutions of the respective alloys.…”
Publicado 2019
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133“…The preparation of anodes with high catalytic activity and long service lifetimes is a core part of electrocatalytic oxidation technology. Here, porous Ti/RuO(2)-IrO(2)@Pt, Ti/RuO(2)-TiO(2)@Pt, and Ti/Y(2)O(3)-RuO(2)-TiO(2)@Pt anodes were fabricated by means of modified micro-emulsion and vacuum impregnation methods with high porosity titanium plates as substrates. …”
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134“…For the appropriate values of its parameters our model reproduces the experimentally found behaviour of Sr2RuO4.…”
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135“…The 10.8 s, 1/2/sup -/ isomer of /sup 93/Ru is shown to be a beta - delayed proton precursor. …”
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136“…Seeking alternative, cost-effective, stable, and possibly reusable catalysts represents a timeless challenge for scientists working in the field. Herein, commercial RuO(2) nanostructures were found to be a robust, versatile, and competitive catalyst in H(2) photoproduction in several conditions. …”
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137por Hou, Zhiying, Lu, Yang, Zhang, Bin, Motiur Rahman, A. F. M., Zhao, Yufen, Xi, Ning, Wang, Ning, Wang, Jinhui“…Ruthenium (Ru)-based organometallic drugs have gained attention as chemotherapeutic and bioimaging agents due to their fewer side effects and excellent physical optical properties. …”
Publicado 2023
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138“…The Ru–Sn bimetallic active center was predominantly located in the Ru-based catalysts. …”
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139por Ma, Weilong, Yang, Xiaoyu, Li, Dingding, Xu, Ruixin, Nie, Liangpeng, Zhang, Baoping, Wang, Yi, Wang, Shuang, Wang, Gang, Diao, Jinxiang, Zheng, Lirong, Bai, Jinbo, Leng, Kunyue, Li, Xiaolin, Qu, Yunteng“…Simultaneously optimizing elementary steps, such as water dissociation, hydroxyl transferring, and hydrogen combination, is crucial yet challenging for achieving efficient hydrogen evolution reaction (HER) in alkaline media. Herein, Ru single atom‐doped WO(2) nanoparticles with atomically dispersed Ru–W pair sites (Ru–W/WO(2)‐800) are developed using a crystalline lattice‐confined strategy, aiming to gain efficient alkaline HER. …”
Publicado 2023
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140Ru–Cu Nanoheterostructures for Efficient Hydrogen Evolution Reaction in Alkaline Water Electrolyzerspor Zuo, Yong, Bellani, Sebastiano, Saleh, Gabriele, Ferri, Michele, Shinde, Dipak V., Zappia, Marilena Isabella, Buha, Joka, Brescia, Rosaria, Prato, Mirko, Pascazio, Roberta, Annamalai, Abinaya, de Souza, Danilo Oliveira, De Trizio, Luca, Infante, Ivan, Bonaccorso, Francesco, Manna, Liberato“…Here, we engineered a hierarchical electrode for the HER composed of amorphous-TiO(2)/Cu nanorods (NRs) decorated with cost-effective Ru–Cu nanoheterostructures (Ru mass loading = 52 μg/cm(2)). …”
Publicado 2023
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