“…The latter ring adopts a boat conformation (with the methyl­triazolylacetate-bearing C atom as the prow and the fused-ring C atoms as the stern). The benzyl groups connected to the diazepinyl ring jprotrude from the sides; the methyl­triazolylacetate substituent occupies an axial position.…”
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“…The mol­ecule of the title compound, C(22)H(23)N(3)O(4), features a benzodiazepine fused-ring system whose seven-membered ring adopts a boat-shaped conformation (with the C atoms of the fused-ring as the stern and the methine C atom as the prow). The methyl­ene C atom connected to the methine C atom occupies an equatorial position. …”
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“…In the two mol­ecules of the asymmetric unit of the title compound, C(12)H(11)N(3)O(4), the seven-membered diazepine ring adopts a boat conformation (with the two phenyl­ene C atoms representing the stern and the methine C atom the prow). The five-membered pyrrole ring, which has an envelope conformation, makes dihedral angles of 60.47 (10) and 54.69 (9)° with the benzene ring of the benzodiazepine unit in the two mol­ecules. …”
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“…The systems resulted in Stern-Volmer plots with k (Q) values of 3.17 × 10(5) and 3.7 × 10(5) M(−1) in the quencher concentration range of 1.5 × 10(−6) to 1.5 × 10(−5) M for human serum albumin (HSA) and bovine serum albumin (BSA), respectively.…”
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“…Binding constant (K(a)), number of binding sites (n), and the binding distance (r) between three RSBs and BSA were calculated by Stern-Volmer equation and Förster’s theory in this study. …”
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“…The SMPBE appears to reproduce the molecular dynamics simulation results better than the PBE only under specific parameter sets, but in general, it performs no better than the Stern layer correction of the PBE. These results emphasize the need for careful discussions of the accuracy of mean-field calculations on realistic systems with respect to the choice of parameters and call for reconsideration of the cost-efficiency and the significance of the current SMPBE formulation.…”
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“…The relationship between the relative fluorescence intensity of carbon dots and the concentration of nitrite was described by the Stern–Volmer equation (I(0)/I − 1 = 0.046[Q]) with a fine linearity (R(2) = 0.99). …”
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“…The results revealed that author Stern Y had the highest number of publications and citations. …”
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“…Extending from an experiment protocol inspired by the Stern-Gerlach experiment in Quantum Physics, we design a crowd-sourced user study to show violation of the Kolmogorovian probability axioms as a proof of the quantum-like structure, and provide a comparison between a quantum probabilistic model and a Bayesian model for predictions of relevance.…”
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“…The intake of microbial-contaminated food poses severe health issues due to the outbreaks of stern food-borne diseases. Therefore, there is a need for precise detection and identification of pathogenic microbes and toxins in food to prevent these concerns. …”
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“…Donor‐substituted psoralens exhibit remarkable photophysical properties, such as high fluorescence quantum yields and pronounced emission solvatochromicity and acidochromicity, which were scrutinized by Lippert–Mataga and Stern–Volmer plots. The results indicate that the compounds exceed the limit of visible light, a significant factor for potential applications as an active agent. …”
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“…If placed on the bow, it becomes exposed to flowing obstacles, and if it is installed on the stern, the redirected water from the boat and its propulsion system change the sensor readings. …”
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“…Two approaches—the double logarithm Stern-Volmer equation and the STAR program—are used to evaluate the binding parameters. …”
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“…The equilibrium association constants for both the complexes have been estimated using Stern–Volmer model.…”
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“…A single-electron transfer process between a protonated aniline and uranyl catalyst, which was disclosed by radical quenching experiments and Stern-Volmer analysis, facilitated the following oxygen atom transfer process between the radical cation of protonated anilines and uranyl peroxide originating from water-splitting. (18)O labeling and (15)N tracking unambiguously depicted that the oxygen came from water and amino group left as ammonium salt. …”
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“…Moreover, the sensitivity and dynamic range, measured with Stern–Volmer analysis, can be tuned two orders of magnitude by virtue of our ability to synthetically control the triplet excited-state ordering. …”
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“…University type and level, teaching-related role overload, scientific research stress induced by promotion, limited job autonomy, a stern hierarchical organizational system, and opaque operating rules are influencing factors discussed. …”
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“…Tuberculosis is a stern, difficult to treat chronic infection caused by acid-fast bacilli that tend to take a long time to be eradicated from the host’s environment. …”
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