“…The structure of the pincer ligand and its palladium complex were stabilised by intramolecular and intermolecular C–H⋅⋅⋅O, C–H⋅⋅⋅N, and N–H⋅⋅⋅N contacts. A Suzuki-Miyaura cross-coupling reaction between aryl halides and phenylboronic acid was used to assess the catalytic abilities of the palladium pincer complexes. …”
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“…A two step synthesis of 2-alkynyl-4-arylquinolines has been accomplished via Pd/C-mediated regioselective C-2 alkynylation of 2,4-dichloroquinoline in water followed by Suzuki coupling at C-4 of the resulting 4-chloro derivative.…”
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“…The Suzuki coupling reaction is one of the most practiced classes of catalytic C-C bond formation. …”
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“…OBJECTIVE: Type 2 diabetes mellitus (T2DM) is a metabolic disease characterized by hyperglycemia, hyperinsulinemia, and complications such as obesity and osteoporosis. The Tsumura, Suzuki, Obese Diabetes (TSOD) mouse is an animal model of spontaneous obese T2DM. …”
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“…The Pd@HHSS catalyst (Pd/SiO(2) = 10 : 100) showed high catalytic activity in Suzuki-reaction with yields of 91–99% and the catalyst is reusable after four successive cycles without obvious loss of catalytic activity.…”
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“…[Image: see text] This work documents the first palladium pincer complex-catalyzed carbonylative Sonogashira (CS) and carbonylative Suzuki–Miyaura (CSM) cross-coupling. Compared to previous protocols, which employ hazardous and toxic solvents, the aminophosphine pincer complex {[C(6)H(3)-2,6-(NHP{piperidinyl}(2))(2)]Pd(Cl)} (III) catalyzes both the cross-coupling reactions in propylene carbonate, an eco-friendly and sustainable polar aprotic solvent. …”
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“…A newly engineered palladacycle that contains substituents on the biphenyl rings along with the ligand HandaPhos is especially well-matched to an aqueous micellar medium, enabling valued Suzuki–Miyaura couplings to be run not only in water under mild conditions, but at 300 ppm of Pd catalyst. …”
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“…Density functional theory (DFT) calculations imply that the facile exergonic dearomative insertion of a naphthalene double bond disrupts the sequence of direct Suzuki coupling, leading to the tandem Heck/Suzuki coupling reaction. …”
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“…The prepared artificial metalloenzyme displayed remarkable activity in Suzuki–Miyaura cross-coupling reaction employing low-palladium loading under mild conditions, with the exceptionally high turnover frequency, clean reaction profile, easy work-up procedure, good to excellent products yields and short reaction times. …”
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“…Herein, we report a general method for Suzuki–Miyaura cross-coupling at 37 °C in aqueous media in the presence of air. …”
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“…A nickel/dppf catalyst system was found to successfully achieve the Suzuki–Miyaura cross-coupling reactions of 3- and 4-chloropyridine and of 6-chloroquinoline but not of 2-chloropyridine or of other α-halo-N-heterocycles. …”
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“…Both bio‐Pd/Ag and bio‐Pd/Au demonstrated greatly enhanced catalytic activity towards Suzuki–Miyaura cross‐coupling compared to a monometallic Pd catalyst, with bio‐Pd/Ag significantly outperforming the others. …”
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“…The Suzuki–Miyaura cross-coupling of C(sp(3))-hybridised boronic compounds still remains a challenging task, thereby hindering the broad application of alkyl boron substrates in carbon–carbon bond-forming reactions. …”
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“…Highly dispersed Pd clusters with an average size of 1.5 nm were constructed on this functional MOFs and behaved excellent catalytic activity in the Suzuki coupling of phenyboronic acid and bromobenzene (yield of biaryl >99%) under mild reaction conditions. …”
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“…The rigid biaryl phosphacycles are efficient for Suzuki–Miyaura cross-coupling of aryl bromides and chlorides. …”
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“…The catalytic performance of HCPs-Pd was evaluated in Suzuki–Miyaura coupling reactions. The results show that HCPs-Pd is a highly active catalyst for the Suzuki–Miyaura coupling reaction in H(2)O/EtOH solvent with TON numbers up to 1.66 × 10(4). …”
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“…A site-selective supported palladium nanoparticle catalyzed Suzuki–Miyaura cross-coupling reaction with heteroaryl esters and arylboronic acids as coupling partners was developed. …”
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