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1“…Unprecedented palladium-catalyzed denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids have been realized, which afforded structurally diverse ortho-amino-substituted biaryl and biaryl ketone derivatives. …”
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5“…The application of the Suzuki-Miyaura reaction in the synthesis of flavonoids, an important class of natural products, is reviewed. …”
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6“…Their use in Stille cross-coupling and Suzuki cross-coupling reactions with organic bromides is demonstrated in yields of 47–94% (Stille cross-coupling) and 0–95% (Suzuki cross-coupling), respectively.…”
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7por Li, Chun-Miao, Geng, Hui-Chun, Li, Ming-Ming, Xu, Gang, Ling, Tie-Jun, Qin, Hong-Bo“…The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone (1) has been achieved. …”
Publicado 2013
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8“…Readily accessed cobalt pre‐catalysts with N‐heterocyclic carbene ligands catalyze the Suzuki cross‐coupling of aryl chlorides and bromides with alkyllithium‐activated arylboronic pinacolate esters. …”
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9por Maity, Ayan, Sulicz, Amanda N., Deligonul, Nihal, Zeller, Matthias, Hunter, Allen D., Gray, Thomas G.“…We report that the palladium-catalyzed Suzuki–Miyaura coupling of arylboronic acids extends to cyclometalated gold(iii) chlorides. …”
Publicado 2015
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10“…The Suzuki-Miyaura reaction (SMR), involving the coupling of an organoboron reagent and an organic halide or pseudo-halide in the presence of a palladium or nickel catalyst and a base, has arguably become one of most utilized tools for the construction of a C-C bond. …”
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11por Guo, Lin, Srimontree, Watchara, Zhu, Chen, Maity, Bholanath, Liu, Xiangqian, Cavallo, Luigi, Rueping, Magnus“…Here, we report an unconventional Suzuki-type approach to the synthesis of biaryls, through nickel-catalyzed deformylative cross coupling of aldehydes with organoboron reagents under base-free conditions. …”
Publicado 2019
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12“…A highly efficient, in situ generated catalyst, PdCl(2)(L(n)@β-CD), was synthesized for palladium-catalyzed cross-coupling reactions under mild reaction conditions, and the use of this catalyst in Suzuki cross-couplings was investigated. Low palladium loadings of 0.01 mol % PdCl(2)(L(n)@β-CD) (Pd accounted for approximately 8.4% of the catalyst by mass) were found to be highly efficient for Suzuki cross-couplings in water and afforded the corresponding biaryl compounds in excellent yields. …”
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13“…Herein, we describe a rhodium‐catalyzed enantio‐ and diastereoselective Suzuki–Miyaura cross‐coupling between racemic fused bicyclic allylic chlorides and boronic acids. …”
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14“…Expanding the carbene precursors to a broader range of starting materials and more diverse products is an ongoing challenge in synthetic organic chemistry. Herein, we report a Suzuki-Miyaura coupling reaction of in situ-generated Pd–carbene complexes via desulfurization of thioureas or thioamides. …”
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15por Matyugina, Elena S., Khandazhinskaya, Anastasia L., Kochetkov, Sergey N., Seley-Radtke, Katherine L.“…1-[tert-Butyl(diphenyl)silyl]pyrrol-3-ylboronic acid was obtained from pyrrole in three steps. Its Suzuki–Miyaura cross-coupling with functionalized pyridinyl and pyrimidinyl bromides afforded new promising 3-hetaryl-1H-pyrroles.…”
Publicado 2020
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16“…Here, we describe the isolation and genome annotation of S. maltophilia siphophage Suzuki. Its 56,042-bp genome has 83 predicted protein-coding genes and demonstrates similarity with Xylella phages Sano and Salvo.…”
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17por Ravbar, Miha, Koler, Amadeja, Paljevac, Muzafera, Krajnc, Peter, Kolar, Mitja, Iskra, JernejEnlace del recurso
Publicado 2022
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18“…The catalytic activity of [(Ph(2)P-o-C(6)H(4))(2)N]PdCl in aerobic aqueous Suzuki couplings is described. Though hydrophobic, this molecular catalyst is competent in cross-coupling reactions of arylboronic acids with a variety of electronically activated, unactivated, and deactivated aryl iodides, bromides, and chlorides upon heating in aqueous solutions under aerobic conditions to give biphenyl derivatives without the necessity of amphiphiles even in the presence of an excess amount of mercury.…”
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19por Saptal, Vitthal B., Saptal, Madhuri V., Mane, Rajendra S., Sasaki, Takehiko, Bhanage, Bhalchandra M.“…This developed catalyst shows a high catalytic activity toward the Suzuki coupling and carbonylative Suzuki–Miyaura coupling reactions at mild reaction conditions. …”
Publicado 2019
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20por Bakhvalova, Elena S., Bykov, Alexey V., Markova, Mariia E., Lugovoy, Yury V., Sidorov, Alexander I., Molchanov, Vladimir P., Sulman, Mikhail G., Kiwi-Minsker, Lioubov, Nikoshvili, Linda Z.“….% of Pd either in the form of Pd(II) species or Pd(0) nanoparticles supported on NA-based polymers were tested in a model reaction of Suzuki cross-coupling between 4-bromoanisole and phenylboronic acid under mild reaction conditions (60 °C, ethanol-water mixture as a solvent). …”
Publicado 2023
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