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4101por Liu, Wei, Wang, Xiting, Wang, Fan, Du, Kaifa, Zhang, Zhaofu, Guo, Yuzheng, Yin, Huayi, Wang, Dihua“…The outstanding HER performances of the MoC–Mo(2)C electrode with low overpotentials at 500 mA cm(−2) in both acidic (256 mV) and alkaline electrolytes (292 mV), long-lasting lifetime of over 2400 h (100 d), and high-temperature performance (70 (o)C) are due to the self-standing hydrophilic porous surface, intrinsic mechanical strength and self-grown MoC (001)–Mo(2)C (101) heterojunctions that have a ΔG(H*) value of −0.13 eV in acidic condition, and the energy barrier of 1.15 eV for water dissociation in alkaline solution. …”
Publicado 2021
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4102por Kumara, Gamaralalage R. A., Pitawala, Herath Mudiyanselage G. T. A., Karunarathne, Buddika, Mantilaka, Mantilaka Mudiyanselage M. G. P. G., Rajapakse, Rajapakse Mudiyanselage G., Huang, Hsin-Hui, De Silva, K. Kanishka H., Yoshimura, Masamichi“…However, X-ray photoelectron spectroscopic (XPS) analysis shows the presence of C–O–C ether functionalities, possibly on edge planes. …”
Publicado 2021
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4103Molecular-level insights into the electronic effects in platinum-catalyzed carbon monoxide oxidationpor Chen, Wenyao, Cao, Junbo, Yang, Jia, Cao, Yueqiang, Zhang, Hao, Jiang, Zheng, Zhang, Jing, Qian, Gang, Zhou, Xinggui, Chen, De, Yuan, Weikang, Duan, Xuezhi“…Diminishing the electron density of Pt consolidates the CO-assisted O(2) dissociation pathway via the O*-O-C*-O intermediate directly observed by isotopic labeling studies and rationalized by density-functional theory calculations. …”
Publicado 2021
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4104“…Energy-dispersive X-ray spectrometry (EDX) analysis of CFB and POB illustrated five main chemical compositions, which were carbon (C), oxygen (O), calcium (Ca), chlorine (Cl), and sodium (Na), whereas Fourier transform infrared (FTIR) spectroscopy analysis identified seven main chemical functional groups, which were O–H, C–H, C=O, C=C, N–H, C–O, and C–Cl. Agar diffusion tests confirmed the abilities of CFB and POB to inhibit both Staphylococcus aureus and Escherichia coli, and batch experiments examined high antibacterial efficiencies of CFB of almost 100% on both bacterial types. …”
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4105por Zamora, Purificación Sánchez, Gallotti, Ana C., Ramos, Raquel, López, Jorge Ligero, González, Yasmina, Mejía, Rossel A., Orozco Vinasco, Adriana C., Fuentes, Isabel, Merino, Francisco J.“…Patient: Male, 39-year-old Final Diagnosis: Amebiasis Symptoms: Temperature of 38ºC • abdomial pain and diarrhea Medication: — Clinical Procedure: — Specialty: Critical Care Medicine OBJECTIVE: Unusual clinical course BACKGROUND: Amebiasis is a parasitic infection caused by the protozoan Entamoeba histolytica. …”
Publicado 2021
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4106“…The presented are, to the best of the authors’ knowledge, the first applications of the ReaxFF approach to the Mn–(Cu|Fe|Ni)–O–C–H interaction.…”
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4107por Goparaju, Praveen V. N. R., Rangnekar, Ameya, Chigh, Amit, Raut, Saijyot Santosh, Kundnani, Vishal“…CONCLUSION: Posterior occipitocervical reconstruction with O-C1-2 TAS construct provided excellent clinical outcomes, radiological outcomes, optimal correction of malalignment in the occipitocervical region, and with biomechanically sound fixation. …”
Publicado 2021
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4108“…Most cellular ATP is made by rotary F(1)F(O) ATP synthases using proton translocation-generated clockwise torque on the F(O) c-ring rotor, while F(1)-ATP hydrolysis can force counterclockwise rotation and proton pumping. …”
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4109por Junior, Luiz-Roberto-Dallari, Baroudi, Kusai, Barroso, Leonardo-dos Santos, Miranda, Milton-Edson, Vitti, Rafael-Pino, Brandt, William-Cunha“…The samples were stored for 24h in distilled water at 37ºC and then were sectioned on a metallographic cutter to obtain tooth picks with approximately 1.0 mm2 in cross section. …”
Publicado 2022
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4110por Ruan, Chongyan, Wang, Xijun, Wang, Chaojie, Zheng, Lirong, Li, Lin, Lin, Jian, Liu, Xiaoyan, Li, Fanxing, Wang, Xiaodong“…The proposed process exhibit near complete NH(3) conversion and exceptional NO selectivity with negligible N(2)O production, using nonprecious V(2)O(5) redox catalyst at 650 (o)C. Operando spectroscopy techniques and density functional theory calculations point towards a modified, temporally separated Mars-van Krevelen mechanism featuring a reversible V(5+)/V(4+) redox cycle. …”
Publicado 2022
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4111por Bamigboye, Comfort Olukemi, Okonji, Raphael E., Oluremi, Iyanu Oluwalonimi, James, Victoria“…RESULTS: The purified amylase has a specific activity of 5.26 U/mg, total activity of 189.20 U, maximally active at 70 °C, pH of 5, and retaining 100% of its activity at 30 (o)C for 4 min. P. tuberregium amylase showed optimal activity with plantain peel, followed by starch and pineapple peel (42, 30, and 29 μg/mL/min respectively). …”
Publicado 2022
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4112por Daud, Adibah Izzati, Khairul, Wan M., Arshad, Suhana, Razak, Ibrahim Abdul, González, Diana L. Nossa, Erben, Mauricio F.“…The Hirshfeld surface analysis has allowed visualizing the crystal packing, which is characterised by the prolonged intermolecular N–H⋯O = C and N–H⋯S = C hydrogen-bonding interactions within Th2 molecule. …”
Publicado 2022
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4113“…The FTIR spectra were collected between 4,000 and 450 cm(–1) and the data in the wavenumber range of 1.175–940 cm(–1), where the deformations of O-H, C-O, C-H, and C=C corresponded to flavanol and phenols, were used for the establishment of PLSR models. …”
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4114por Cao, Dawei, Ataya, Mohamad, Chen, Zhangpei, Zeng, Huiying, Peng, Yong, Khaliullin, Rustam Z., Li, Chao-Jun“…Although transition−metal−catalyzed decarbonylation of unstrained diaryl ketones provides a viable protocol to construct biaryl structures, the use of expensive catalyst and high temperature (>140 (o)C) have greatly limited their universal applicability. …”
Publicado 2022
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4115“…Four tetranuclear heterobimetallic triangle complexes [L(3)Co(3)Dy(NO(3))(2)(H(2)O)(MeOH)(5)](NO(3)) (C1), [L(3)Co(3)Gd(NO(3))(3)(MeOH)(4)] (C2), [L(3)Co(3)La(NO(3))(2)(H(2)O)(6)](NO(3))(H(2)O) (C3), and [L(3)Co(3)TbCl(NO(3))(2)(H(2)O)(0.5)(MeOH)(3.5)] (C4), where H(2)L = 1,4-bisformylnaphthalene-2,3-diol, have been synthesised and structurally characterised. …”
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4116“…Biochar C mineralization was positively correlated with an increase in O/C ratio post-ageing (r(s) = 0.86, p value = 0.01). …”
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4117por Bhattacharyya, Manjit K., Saha, Utpal, Dutta, Debajit, Das, Amal, Verma, Akalesh K., Frontera, Antonio“…The structural topology of the complexes is established by the interplay of strong O–H⋯O and weak C–H⋯O, C–H⋯C, π–π stacking interactions. Unconventional parallel intramolecular and anti-parallel intermolecular contacts involving the chelate rings (CR) also stabilize the structures. …”
Publicado 2019
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4118“…All the spectra exhibited the characteristic bands of –C–H, –C[double bond, length as m-dash]O, –C–O– and [double bond, length as m-dash]CH(2), in which 11 common bands as independent variables were selected to establish various FTIR characteristic–quality relationship models. …”
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4119por Chuliá-Jordán, R., Santamaría-Pérez, D., González-Platas, J., Otero-de-la-Roza, A., Ruiz-Fuertes, J., Popescu, C.“…The experimental observation of the high-pressure phase up to 15 GPa and 300 ºC suggests that the decomposition into its single carbonate components is kinetically hindered.…”
Publicado 2022
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4120“…After bonding, the teeth were stored in artificial saliva at 37(º)C for 24 hours and debonded with a universal testing machine. …”
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