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2021“…In the risperidone cation of the title compound, C(23)H(28)FN(4)O(2) (+)·NO(3) (−), the piperidine ring adopts a chair conformation and the tetrahydropyridine ring is disordered over two orientations in a 0.620 (11):0.380 (11) ratio. N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds are present in the crystal structure.…”
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2022“…In the crystal structure, the molecules are linked into a three-dimensional network via C—H⋯O, C—H⋯N, N—H⋯O, N—H⋯S and O—H⋯O hydrogen bonds.…”
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2023por Zukerman-Schpector, Julio, Sousa Madureira, Lucas, Rodrigues, Alessandro, Vinhato, Elisângela, Olivato, Paulo R.“…Molecules are sustained in the three-dimensional structure by a combination of C—H⋯O, C—H⋯π and π–π [shortest centroid–centroid distance = 3.672 (6) Å] interactions.…”
Publicado 2009
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2024“…In the crystal structure of the title proton-transfer compound, CH(6)N(3)O(+)·C(7)H(4)NO(4) (−), O—H⋯O and N—H⋯O hydrogen bonds are formed respectively between the cations and the anions, each component affording a supramolecular chain along the c axis. …”
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2025“…The asymmetric unit of the title compound, C(19)H(12)Cl(2)O, contains four independent molecules, which can be divided into two pairs of molecules with close values of the C—C(=O)—C=C torsion angles in each pair, viz. 165.12 (16) and 165.68 (15)° in one pair, and −164.66 (15) and −164.81 (15)° in the other pair. …”
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2026“…An intramolecular N—H⋯O=C hydrogen bond is observed. In the crystal, molecules are connected into layers parallel to (10[Image: see text]) by a classical intermolecular hydrogen bond from the second NH group to a nitro O atom and by three weak hydrogen bonds of the C—H⋯X type (X = O or S(thione)).…”
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2027“…The planes of the two benzene rings in the molecule of the title compound, C(13)H(11)BF(2)O(3), form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is −79.20 (1)°. …”
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2028por Naveenkumar, H. S., Sadikun, Amirin, Ibrahim, Pazilah, Loh, Wan-Sin, Fun, Hoong-Kun“…The methoxy group is slightly twisted away from the attached ring [C—O—C—C = 7.5 (2)°]. In the crystal structure, molecules are linked into a three-dimensional network by intermolecular N—H⋯N and C—H⋯O hydrogen bonds. …”
Publicado 2009
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2029“…The methoxy groups are coplanar with the benzene ring to which they are attached [C—C—O—C = 1.0 (6)°]. The two furan rings are inclined at 17.3 (3)° with respect to each other and the dihedral angle between the furan ring and the benzene ring is 75.83 (12)°. …”
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2030por Das, Subrata, Saikia, Binoy K., Das, Babulal, Saikia, Lakhinath, Thakur, Ashim J.“…The packing is stabilized by N—H⋯O, C—H⋯O and C—H⋯N interactions.…”
Publicado 2009
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2031por Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef, Shakuntala, K., Fuess, Hartmut“…In addition, there is a carbonyl–carbonyl dipolar interaction with an O⋯C contact of 2.926 (3) Å.…”
Publicado 2009
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2032“…The indole plane is significantly less twisted from the plane of the central C—C(=O)—C bridge than the benzene plane [dihedral angles = 15.51 (3) and 40.13 (7)°, respectively]. …”
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2033por Bardin, Julie, Florence, Alastair J., Arlin, Jean-Baptiste, Kennedy, Alan R., Wong, Li Ven“…In the crystal of the title compound, C(6)H(7)N(2)O(+)·C(2)HF(2)O(2) (−), the cation adopts a catemeric N—H⋯O hydrogen-bonded chain motif involving the carboxamide group, with two further N—H⋯O hydrogen bonds connecting the cations to adjacent difluoroacetate anions via the carboxamide and pyridinium N atoms. …”
Publicado 2009
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2034“…Three intramolecular C—H⋯O, C—H⋯N and N—H⋯O hydrogen-bond interactions are present. …”
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2035“…The title compound, [Al(CH(3))(2)(C(25)H(21)N(2)O)(C(4)H(8)O)], was isolated as a minor component from a reaction mixture of the parent indolyl ligand and trimethylaluminum in tetrahydrofuran. …”
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2036“…In the title salt, C(11)H(14)N(3)O(+)·C(7)H(5)O(3) (−), the phenyl ring of the cation is oriented at an angle of 67.0 (1)° with respect to the five-membered pyrazolone ring. …”
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2037“…The molecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both molecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in trans-configured cyclohexane derivatives (including pyranoses) as well as rac-trans-cycloheptane-1,2-diol, but smaller than those in trans-configured cyclopentane derivatives (including furanoses). …”
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2038“…Intermolecular N—H⋯S, N—H⋯O, C—H⋯O and C—H⋯S hydrogen bonds are found in the crystal structure.…”
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2039“…The two methoxy groups are approximately coplanar with the attached benzene ring [C—O—C—C = −2.7 (4) and 9.4 (4)°]. The dihedral angle between the two aromatic rings is 67.16 (12)°. …”
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2040“…The title compound, C(15)H(19)NO(4), contains one crystallographically independent molecule in the asymmetric unit. The N—O—C—O torsion angle is 1.97 (9)°. The two pairs of vicinal H atoms that lie above or below the plane defined by the five-membered pyrrolidine-2,5-dione ring are an average of 6.57 (5)° from being eclipsed. …”
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