“…Proton NMR spectra indicate that on the NMR time scale there is rapid rotation of the cyclopentadienyl ring around the metal-ring axis at 25ºC. Studies were conducted to assess the growth inhibiting potential of the complexes synthesized and the ligands against various bacterial strains.…”
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“…In addition the high acidity (4.0 mmol/g), thermal stability (200 ºC) and easy reusability make the novel catalyst one of the best choices for the process.…”
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“…The required chiral o-alkynylphosphinic amide starting materials were prepared in high yields under very mild reaction conditions through alkynylation of P-stereogenic (O^C)-cyclometalated (phosphinic amide)dichlorogold(III) complexes and Sonogashira cross-coupling of ortho-iodo P-stereogenic phosphinic amide.…”
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“…Infinite ribbons of N—H⋯O=C-connected mol­ecules represent the basic supra­molecular entities of the crystal structure. …”
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“…The interaction energy is enhanced to ≤–5 kcal·mol(−1) when X is more electron withdrawing such as in [O(2)N-CH(3)··O=C(dme)] (20b) and to ≤18 kcal·mol(−1) in cationic species like [Me(3)O(+)-CH(3)···OH(2)](+) (8a).…”
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“…Two classical hydrogen bonds from the amine group, one of the form N—H⋯O=S and one N—H⋯O=C(oxo), link the mol­ecules to form layers parallel to the bc plane.…”
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“…San Antonio Oeste constitutes the southernmost finding for the continent (40º44’S), whereas Tandil is the infested locality with the coldest mean annual temperature in Argentina (14.17ºC). The projection of a previous distribution model for Ae. aegypti predicts these two cities as positive and suggests several other localities with suitable conditions for vector proliferation beyond its assumed distribution limits.…”
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“…Our calculated results show excellent agreement with the available data for the two polysaccharides and demonstrate that the use of the CPWF approach at the AM1 and PM3 levels of approximation provides a convenient and reliable method for the study of infinitely periodic bonds of two different types: moderately strong O–H···O hydrogen bonding and strong C–O–C covalent bonding.…”
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“…The salicyl­aldehyde engages in intra­molecular hydrogen bonding with an O—H⋯O distance of 2.6231 (19) Å while the mol­ecules pack together via weak inter­molecular C—H⋯O, C—H⋯F and F⋯O inter­actions and offset face-to-face π-stacking.…”
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“…o-Carboryne (1,2-dehydro-o-carborane) is a very useful synthon for the synthesis of a variety of carborane-functionalized molecules. With 1-Li-2-OTf-o-C(2)B(10)H(10) as the precursor, o-carboryne undergoes an efficient [4 + 2] cycloaddition with various conjugated enynes, followed by a subsequent [2 + 2] cycloaddition at room temperature, generating a series of carborane-fused tricyclo[6.4.0.0(2,7)]dodeca-2,12-dienes in moderate to high isolated yields. …”
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“…XPS support Raman and verify the C–O/C–N formations in carbon lattices. Electrical measurements show an unipolar p-type character as probes are placed in contact with untreated regions of nanotubes. …”
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“…The meth­oxy group attached to the benzene ring is slightly twisted [C—C—O—C = −15.2 (1)°] from the ring. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into C(7) chains propagating along [101]. …”
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“…The (P(III), P(IV), P(V)) phosphorus atom in organophosphorus groups is linked to the acene directly by a P-C(sp2) bond or indirectly through an oxygen atom by a P-O-C(sp2) bond.…”
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“…The increase in functionalization duration induced the rise of O/C from 0.28 to 0.335, an increase in sensor resistance, and the distortion of the shape of the I-V curves.…”
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“…The meth­oxy groups at the ortho and meta positions of the benzene ring are tilted to the ring with C—C—O—C torsion angles of 105.9 (4) and 9.5 (5)°, respectively. …”
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“…Mass fluxes ranging from 100 to 500 kg/(m^2 s), heat fluxes from 15 to 55 kW/m^2, vapour qualities between 0.05 and 0.80, and saturation temperatures of 35, 41 and 47ºC were considered in the 300-point experimental database. …”
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“…Estudio autorizado por el comité de ética de la Facultad de Odontología. 5 mg de SB15 fueron depositados en 0.5 mL de plasma de un adulto sano; la muestra fue incubada por 15 minutos a 37ºC en agitación (50 rpm; por triplicado). Los 10 mg de SB15 fueron depositados en 0.5 mL de plasma de un adulto sano; la muestra fue incubada por 15 minutos a 37ºC en agitación (50 rpm; por triplicado). …”
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“…Notably, the T(5%) and T(50%) of 3%-ZnO@PDA/PLA increased by 36.4 (o)C and 31.9 (o)C. GPC results showed the molecular weight of 3%-ZnO@PDA/PLA was only reduced by 15.8% after thermal processing. …”
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“…Our results show that NE could be used to maintain ram spermatozoa during transport at 15 and 22 ºC for up to 96 h, with no appreciable loss of kinematic and physiological characteristics of freshly collected samples. …”
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“…By contrast, reaction of 1 with [CPh(3)][B(C(6)F(5))(3)] in C(6)D(5)Br/toluene or o-C(6)H(4)F(2)/toluene afforded dicationic [(XII(2))Sc(CH(2)SiMe(3))(η(x)-toluene)(n)][B(C(6)F(5))(4)](2) (5). …”
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